The influence of silicon-containing acrylate as active diluent on the properties of UV-cured epoxydiacrylate films
文献类型：期刊论文
| 作者 | Liu, HB; Chen, MC; Huang, ZT; Xu, K; Zhang, XJ |
| 刊名 | EUROPEAN POLYMER JOURNAL
 |
| 出版日期 | 2004-03-01 |
| 卷号 | 40期号:3页码:609-613 |
| 关键词 | Uv-curable Epoxydiacrylate Silicon Films Photopolymerization Diluent |
| ISSN号 | 0014-3057 |
| DOI | 10.1016/j.eurpolymj.2003.10.018 |
| 英文摘要 | A new silicon-containing acrylate, which can be a good active diluent for UV-curable epoxydiacrylate systems, was prepared by reacting N-cyclohexyl-gamma-aminopropylmethyldimethoxysilane (CAMS) with trimethylolpropane triacrylate (TMPTA) by Michael-type addition reaction. The reactivity of -NH groups of CAMS with the acrylic groups of TMPTA was characterized by FTIR. The contents of the new active diluent in the UV-cured polymeric films were varied between 5% and 15% by weight. Mechanical, physical, and thermal characterizations of the UV-cured films were investigated: An increase in silicon-containing acrylate content caused a dramatic change of the surface properties of the films, and a decrease in mechanical properties besides the relative elongation. Thermogravimetric analysis of silicon-containing acrylate revealed that incorporating silicon into the structure resulted in a high char yield at 700 C. Water absorption values of UV-cured films were also affected by the amount of silicon-containing acrylate. (C) 2003 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000189257100019 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82359]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, HB |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Chem, Polymer Div 7, Guangzhou 510650, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, HB,Chen, MC,Huang, ZT,et al. The influence of silicon-containing acrylate as active diluent on the properties of UV-cured epoxydiacrylate films[J]. EUROPEAN POLYMER JOURNAL,2004,40(3):609-613. |
| APA | Liu, HB,Chen, MC,Huang, ZT,Xu, K,&Zhang, XJ.(2004).The influence of silicon-containing acrylate as active diluent on the properties of UV-cured epoxydiacrylate films.EUROPEAN POLYMER JOURNAL,40(3),609-613. |
| MLA | Liu, HB,et al."The influence of silicon-containing acrylate as active diluent on the properties of UV-cured epoxydiacrylate films".EUROPEAN POLYMER JOURNAL 40.3(2004):609-613. |
入库方式： OAI收割
来源：化学研究所
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