Facile synthesis of exfoliated and highly conductive poly(arylene disulfide)/graphite nanocomposites
文献类型:期刊论文
作者 | Du, XS; Xiao, M; Meng, YZ; Hay, AS |
刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
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出版日期 | 2004-06-01 |
卷号 | 15期号:6页码:320-323 |
关键词 | Macrocyclics Ring-opening Polymerization Nanocomposites Conductivity Exfoliated Graphite |
ISSN号 | 1042-7147 |
DOI | 10.1002/pat.457 |
英文摘要 | Exfoliated graphite has been synthesized by first synthesizing H2SO4 intercalated compound in a H2O2-H2SO4 mixture, followed by exfoliation under microwave irradiation. Poly(arylene disulfide)/ graphite nanocomposites were then fabricated by absorbing cyclic(arylene disulfide) oligomers into the pores of exfoliated graphite. Subsequently, the nanocomposite precursor was subjected to heat treatment to carry out the in situ ring-opening polymerization of the oligomers via free radical mechanism. The as-prepared nanocomposite exhibited a exfoliated nanostructure as evidenced by transmission electron microscopy (TEM) observation. The nanocomposite with a very small amount of graphite, 5 wt%, possesses a highly electrical conductivity of 4 S/cm, therefore, many applications can be found as conductive materials. Copyright (C) 2004 John Wiley Sons, Ltd. |
语种 | 英语 |
WOS记录号 | WOS:000221802200005 |
出版者 | JOHN WILEY & SONS LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/82363] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Meng, YZ |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Zhongshan Sun Yat Sen Univ, Sch Phys & Engn, Guangzhou 510275, Peoples R China 3.McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada |
推荐引用方式 GB/T 7714 | Du, XS,Xiao, M,Meng, YZ,et al. Facile synthesis of exfoliated and highly conductive poly(arylene disulfide)/graphite nanocomposites[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2004,15(6):320-323. |
APA | Du, XS,Xiao, M,Meng, YZ,&Hay, AS.(2004).Facile synthesis of exfoliated and highly conductive poly(arylene disulfide)/graphite nanocomposites.POLYMERS FOR ADVANCED TECHNOLOGIES,15(6),320-323. |
MLA | Du, XS,et al."Facile synthesis of exfoliated and highly conductive poly(arylene disulfide)/graphite nanocomposites".POLYMERS FOR ADVANCED TECHNOLOGIES 15.6(2004):320-323. |
入库方式: OAI收割
来源:化学研究所
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