Synthesis and characterization of mono- and dinuclear nickel complexes with dichalcogenolate o-carboranyl ligands
文献类型：期刊论文
| 作者 | Yu, XY; Lu, SX; Jin, GX; Weng, LH |
| 刊名 | INORGANICA CHIMICA ACTA
 |
| 出版日期 | 2004-01-30 |
| 卷号 | 357期号:2页码:361-366 |
| 关键词 | Nickel Complexes Crystal Structures Dichalcogenolate O-carborane |
| ISSN号 | 0020-1693 |
| DOI | 10.1016/j.ica.2003.05.001 |
| 英文摘要 | Three mono- and dinuclear nickel complexes with dichalcogenolate o-carboranyl ligands were synthesized and characterized by X-ray crystallography. The reactions of Ni(COD)(2)(COD=1,5-octadiene) with [(THF)(3)LiE2)C2B10H10Li(THF)](2) (E = S, Se) in THF in the presence of air in different ratios afforded the mono- and dinuclear nickel complexes of formulae Li(THF)(4)](2)[Ni(E2C2B10H10)(2)] (E=S, la; E=Se, 1b) and [Li(THF)(4)](2)[Ni-2(E(2)CZB(10)H(10))(3)] (E=S, 2a; E=Se, 2b). In 2a, two nickel atoms are connected by one chalcogen (eta(1),eta(2)-S2C2B10H10) bridging ligand with strong metal-metal interaction. Complex of formula (PPh3)(2)Ni(S2C2B10H10).0.5THF (3a) was also obtained from the reaction of (PPh3)(2)NiCl2 and [(THF)(3)LiS2C2B10H10Li(THF)](2). (C) 2003 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000188715300003 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82401]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jin, GX |
| 作者单位 | 1.Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, XY,Lu, SX,Jin, GX,et al. Synthesis and characterization of mono- and dinuclear nickel complexes with dichalcogenolate o-carboranyl ligands[J]. INORGANICA CHIMICA ACTA,2004,357(2):361-366. |
| APA | Yu, XY,Lu, SX,Jin, GX,&Weng, LH.(2004).Synthesis and characterization of mono- and dinuclear nickel complexes with dichalcogenolate o-carboranyl ligands.INORGANICA CHIMICA ACTA,357(2),361-366. |
| MLA | Yu, XY,et al."Synthesis and characterization of mono- and dinuclear nickel complexes with dichalcogenolate o-carboranyl ligands".INORGANICA CHIMICA ACTA 357.2(2004):361-366. |
入库方式： OAI收割
来源：化学研究所
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