Properties of a new synthetic rubber: High-trans 1,4-poly(butadiene-co-isoprene) rubber
文献类型：期刊论文
| 作者 | He, AH; Yao, W; Huang, BC; Huang, YQ; Jiao, SK |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2004-06-05 |
| 卷号 | 92期号:5页码:2941-2948 |
| 关键词 | Conjugated Polymers Rubber Vulcanization Mechanical Properties |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.20256 |
| 英文摘要 | A high-trans 1,4-butadiene/isoprene copolymer (TBIP) was synthesized in a 5-L autoclave with hydrogen as an effective molecular weight modifier. The effects of hydrogen on the catalyst efficiency and molecular weight of the copolymers were investigated. The processability and physicomechanical properties of TBIP and their relationship to the composition, composition distribution, and molecular weight of TBIP were examined in detail. Increasing the H, pressure effectively reduced the molecular weight of TBIP. The optimum Mooney viscosity of TBIP and the 1,4-butadiene molar content in the feed were 30-50 and 5-25%, respectively. No cis-trans isomerization was observed during the roll processing procedure for TBIP. The vulcanization characteristics of TBIP were similar to those of general rubbers, and no reverse vulcanization was observed for TBIP. A high green strength was the typical characteristic of TBIP. Vulcanized TBIP (TBIR) with an optimum composition and molecular weight presented outstanding antifatigue properties and low heat buildup in comparison with general rubbers. Compared with general sidewall stock [natural rubber (NR)/butadiene rubber (BR) = 50/50], TBIR exhibited a greater than 15-fold increase in its crack-initiation resistance. The other mechanical properties of TBIR were similar to those of 50/50 NR/BR. The heat-aging mechanism of TBIR was crosslinking aging. (C) 2004 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000220759400023 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82425]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | He, AH |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China 2.Qingdao Univ Sci & Technol, Coll Polymer Sci & Engn, Qingdao 266042, Peoples R China 3.Beijing Univ Chem Technol, Coll Mat Sci & Engn, Beijing 100029, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, AH,Yao, W,Huang, BC,et al. Properties of a new synthetic rubber: High-trans 1,4-poly(butadiene-co-isoprene) rubber[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2004,92(5):2941-2948. |
| APA | He, AH,Yao, W,Huang, BC,Huang, YQ,&Jiao, SK.(2004).Properties of a new synthetic rubber: High-trans 1,4-poly(butadiene-co-isoprene) rubber.JOURNAL OF APPLIED POLYMER SCIENCE,92(5),2941-2948. |
| MLA | He, AH,et al."Properties of a new synthetic rubber: High-trans 1,4-poly(butadiene-co-isoprene) rubber".JOURNAL OF APPLIED POLYMER SCIENCE 92.5(2004):2941-2948. |
入库方式： OAI收割
来源：化学研究所
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