Anionic non-equilibrium ring-opening polymerization of octamethylcyclotetrasiloxane (D-4) initiated by silazyl-lithiums
文献类型：期刊论文
| 作者 | Su, SX; Zhang, ZJ; Zheng, ZM; Xie, ZM |
| 刊名 | POLYMER INTERNATIONAL
 |
| 出版日期 | 2004-02-01 |
| 卷号 | 53期号:2页码:149-152 |
| 关键词 | Anionic Non-equilibrium Polymerization Polysiloxane Silazyl-lithium Molecular Weight Distribution |
| ISSN号 | 0959-8103 |
| DOI | 10.1002/pi.1041 |
| 英文摘要 | The initiation and propagation reactions in anionic non-equilibrium polymerization of octamethylcyclotetrasiloxane (D-4) initiated by silazyl-lithiums are investigated. It is found that: both the steric hindrance effect and the electronic effect of the substitutes on the Si atom Si influences the initiation activity of silazyl-lithiums; temperature effect on the propagation rate of D-4 increases strongly above 40degreesC; the molecular weight distribution of the prepared polysiloxanes widens with time. (C) 2003 Society of Chemical Industry. |
| 语种 | 英语 |
| WOS记录号 | WOS:000188301700005 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82429]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, ZJ |
| 作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Engn Plast, Ctr Mol Sci,Grp 404, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Su, SX,Zhang, ZJ,Zheng, ZM,et al. Anionic non-equilibrium ring-opening polymerization of octamethylcyclotetrasiloxane (D-4) initiated by silazyl-lithiums[J]. POLYMER INTERNATIONAL,2004,53(2):149-152. |
| APA | Su, SX,Zhang, ZJ,Zheng, ZM,&Xie, ZM.(2004).Anionic non-equilibrium ring-opening polymerization of octamethylcyclotetrasiloxane (D-4) initiated by silazyl-lithiums.POLYMER INTERNATIONAL,53(2),149-152. |
| MLA | Su, SX,et al."Anionic non-equilibrium ring-opening polymerization of octamethylcyclotetrasiloxane (D-4) initiated by silazyl-lithiums".POLYMER INTERNATIONAL 53.2(2004):149-152. |
入库方式： OAI收割
来源：化学研究所
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