中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Thermal stability and flammability of polypropylene/montmorillonite composites

文献类型:期刊论文

作者Qin, HL; Zhang, SM; Zhao, CG; Feng, M; Yang, MS; Shu, ZJ; Yang, SS
刊名POLYMER DEGRADATION AND STABILITY
出版日期2004-08-01
卷号85期号:2页码:807-813
关键词Polypropylene Montmorillonite Thermal Stability Flammability Char
ISSN号0141-3910
DOI10.1016/j.polymdegradstab.2004.03.014
英文摘要Smectite clays.. such as montmorillonite, are of great industrial value because of their high aspect ratio, plate morphology, intercalative capacity.. natural abundance and low cost. In the present work, polypropylene/montmorillonite (PP/MMT) composites have been prepared and their thermal stability and flammability have been investigated. Although the composites are not nanodispersed, they exhibit higher thermal stability and considerably reduced peak heat release rate (PHRR). This is probably due to physico-chemical adsorption of the volatile degradation products on the silicates. On the other hand, the addition of MMT can catalyse the initial decomposition of PP matrix and accelerate its ignition in combustion. It has been observed that a ceramic-like char formed on the surface of the composites during the combustion test. The characterization of the char surface prior to ignition indicates that it is an inorganic-rich surface, leading to improvement of the thermal stability and reduction of flammability of the composites because of its better barrier properties. (C) 2004 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000223254300008
出版者ELSEVIER SCI LTD
源URL[http://ir.iccas.ac.cn/handle/121111/82495]  
专题中国科学院化学研究所
通讯作者Zhang, SM
作者单位1.Chinese Acad Sci, Ctr Mol Sci, State Key Lab Engn Plast, Inst Chem, Beijing 100080, Peoples R China
2.Chinese Peoples Armed Police Force Acad, Dept Fire Protect Engn, Langfang 065000, Hebei, Peoples R China
推荐引用方式
GB/T 7714
Qin, HL,Zhang, SM,Zhao, CG,et al. Thermal stability and flammability of polypropylene/montmorillonite composites[J]. POLYMER DEGRADATION AND STABILITY,2004,85(2):807-813.
APA Qin, HL.,Zhang, SM.,Zhao, CG.,Feng, M.,Yang, MS.,...&Yang, SS.(2004).Thermal stability and flammability of polypropylene/montmorillonite composites.POLYMER DEGRADATION AND STABILITY,85(2),807-813.
MLA Qin, HL,et al."Thermal stability and flammability of polypropylene/montmorillonite composites".POLYMER DEGRADATION AND STABILITY 85.2(2004):807-813.

入库方式: OAI收割

来源:化学研究所

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