Infrared study on in situ polymerization of zinc dimethacrylate in poly(alpha-octylene-co-ethylene) elastomer
文献类型：期刊论文
| 作者 | Lu, YL; Liu, L; Shen, DY; Yang, C; Zhang, L |
| 刊名 | POLYMER INTERNATIONAL
 |
| 出版日期 | 2004-06-01 |
| 卷号 | 53期号:6页码:802-808 |
| 关键词 | Infrared Spectroscopy In Situ Polymerization Zinc Dimethacrylate Poly(Alpha-octylene-co-ethylene) |
| ISSN号 | 0959-8103 |
| DOI | 10.1002/pi.1462 |
| 英文摘要 | An infrared spectroscopic method was used to follow the course of in situ polymerization of zinc dimethacrylate (ZDMA) in poly(alpha-octylene-co-ethylene) elastomer (POE). The integral intensity of the 831 cm(-1) band, ie the out-of-plane deformation mode of =CH, was used to determine the residual amount of ZDMA in composites cured at 165degreesC for different times, through which the course of in situ polymerization of ZDMA in POE was traced and the dynamic curve determined. The curing course of the ZDMA/POE/peroxide system at 165degreesC was examined with a rheometer and compared with the course of in situ polymerization. The results surprisingly show that the in situ polymerization of ZDMA is almost complete at the beginning stage of curing, and that substantial crosslinking starts subsequently. Scanning electron microscopy and transmission electron microscopy observations on morphologies of ZDMA/POE composites cured at 165degreesC for different times were carried out and confirmed the results of infrared experiments. Combining all the investigations, it was deduced that a competition exists between in situ polymerization and crosslinking in the composites. Covalent crosslinking rather than ionic bond crosslinks are the major types of crosslinks structures in ZDMA/POE composites, and its total density is lower than that of carbon- black-reinforced POE. (C) 2004 Society of Chemical Industry. |
| 语种 | 英语 |
| WOS记录号 | WOS:000221509500026 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82543]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, L |
| 作者单位 | 1.Beijing Univ Chem Technol, Key Lab Beijing City Preparat & Proc Novel Polyme, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol, Joint Lab Polymer Sci & Mat,State Key Lab Polymer, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, YL,Liu, L,Shen, DY,et al. Infrared study on in situ polymerization of zinc dimethacrylate in poly(alpha-octylene-co-ethylene) elastomer[J]. POLYMER INTERNATIONAL,2004,53(6):802-808. |
| APA | Lu, YL,Liu, L,Shen, DY,Yang, C,&Zhang, L.(2004).Infrared study on in situ polymerization of zinc dimethacrylate in poly(alpha-octylene-co-ethylene) elastomer.POLYMER INTERNATIONAL,53(6),802-808. |
| MLA | Lu, YL,et al."Infrared study on in situ polymerization of zinc dimethacrylate in poly(alpha-octylene-co-ethylene) elastomer".POLYMER INTERNATIONAL 53.6(2004):802-808. |
入库方式： OAI收割
来源：化学研究所
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