Synthesis, Fourier-transform Raman and infrared spectroscopic analysis, and crystal structure of (NiL)(2), (L = bis(2,4-dimethyldipyrrin-3-yl)methane)
文献类型：期刊论文
| 作者 | Shan, XF; Yang, LY; Li, W; Chen, QQ; Wang, ZP; Hu, JM; Ma, JS |
| 刊名 | JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
 |
| 出版日期 | 2004-07-01 |
| 卷号 | 34期号:7页码:433-439 |
| 关键词 | Synthesis Crystal Structure Ni(Ii) Complex Dipyrrin Raman Spectroscopy Infrared Spectroscopy |
| ISSN号 | 1074-1542 |
| 英文摘要 | The Ni(II) complex with bis(2,4-dimethyldipyrrin-3-yl) methane, (NiL)(2), has been synthesized and characterized by H-1-NMR, UV-Vis, FT-IR, FT-Raman, MS, and elemental analysis. X-ray diffraction analysis at room temperature indicates that the complex crystallizes in triclinic system, space group P - 1 with a = 11.344( 4), b = 12.703( 4), c = 14.936( 5) Angstrom, alpha = 87.017(6) degrees, beta = 75.379(5) degrees, gamma = 75.318(5)degrees, M-r = 826.31, V = 2014.5(11) Angstrom(3), Z = 2. The crystal structure of the title complex reveals that it is a dinuclear double-stranded helical entity. The ligands perform as tetradentate ligands and the ratio of Ni( II) to ligand is 2: 2. The central Ni( II) atom is tetracoordinated by four nitrogen donors of two ligands and the coordination geometry of Ni( II) can be considered as a distorted tetrahedron configuration. The IR and Raman spectral analysis, assignment, and discussion are presented. |
| 语种 | 英语 |
| WOS记录号 | WOS:000222800700005 |
| 出版者 | KLUWER ACADEMIC/PLENUM PUBL |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/82563]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ma, JS |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China 2.Wuhan Univ, Dept Anal Measurement Sci, Wuhan 430072, Peoples R China 3.Harbin Engn Univ, Dept Chem Engn, Harbin 150001, Peoples R China 4.Biomarin Pharmaceut Inc, Novato, CA 94949 USA |
| 推荐引用方式 GB/T 7714 | Shan, XF,Yang, LY,Li, W,et al. Synthesis, Fourier-transform Raman and infrared spectroscopic analysis, and crystal structure of (NiL)(2), (L = bis(2,4-dimethyldipyrrin-3-yl)methane)[J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY,2004,34(7):433-439. |
| APA | Shan, XF.,Yang, LY.,Li, W.,Chen, QQ.,Wang, ZP.,...&Ma, JS.(2004).Synthesis, Fourier-transform Raman and infrared spectroscopic analysis, and crystal structure of (NiL)(2), (L = bis(2,4-dimethyldipyrrin-3-yl)methane).JOURNAL OF CHEMICAL CRYSTALLOGRAPHY,34(7),433-439. |
| MLA | Shan, XF,et al."Synthesis, Fourier-transform Raman and infrared spectroscopic analysis, and crystal structure of (NiL)(2), (L = bis(2,4-dimethyldipyrrin-3-yl)methane)".JOURNAL OF CHEMICAL CRYSTALLOGRAPHY 34.7(2004):433-439. |
入库方式： OAI收割
来源：化学研究所
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