Developments in compartmentalized bimetallic transition metal ethylene polymerization catalysts
文献类型：期刊论文
| 作者 | Suo, HY; Solan, GA; Ma, YP; Sun, WH
|
| 刊名 | COORDINATION CHEMISTRY REVIEWS
 |
| 出版日期 | 2018-10-01 |
| 卷号 | 372页码:101-116 |
| 关键词 | Bimetallic complex Early transition metal Late transition metal Catalyst Compartmental ligand Ethylene polymerization Polyethylene microstructure |
| ISSN号 | 0010-8545 |
| DOI | 10.1016/j.ccr.2018.06.006 |
| 英文摘要 | Recent progress concerning the application of compartmentalized bimetallic complexes as homogeneous catalysts in ethylene polymerization is reviewed with particular regard to metal-metal combinations based on either early- (Ti, Zr, Hf and V) or late-transition metals (Fe, Co and Ni). The effect of positioning two polymerization-active metal centers in close proximity on catalytic activity, molecular weight, molecular weight distribution and levels of branching are thoroughly documented. Compartmental ligands comprising binding domains consisting of phenoxyimines, ansa-bridged cyclopentadienyl-amides, alpha-diimines and iminopyridines are described as is their capacity to serve as compatible binucleating supports for homobimetallic and also for the less investigated heterobimetallic counterparts. By comparison with their mononuclear analogues, any synergic properties exhibited by these binuclear catalysts represents an underlying theme to be developed where possible throughout this review. (C) 2018 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000439683000006 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/41963]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Solan, GA 2.Sun, WH (reprint author), Chinese Acad Sci, Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China. 3.Solan, GA 4.Sun, WH (reprint author), Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Suo, HY,Solan, GA,Ma, YP,et al. Developments in compartmentalized bimetallic transition metal ethylene polymerization catalysts[J]. COORDINATION CHEMISTRY REVIEWS,2018,372:101-116. |
| APA | Suo, HY,Solan, GA,Ma, YP,&Sun, WH.(2018).Developments in compartmentalized bimetallic transition metal ethylene polymerization catalysts.COORDINATION CHEMISTRY REVIEWS,372,101-116. |
| MLA | Suo, HY,et al."Developments in compartmentalized bimetallic transition metal ethylene polymerization catalysts".COORDINATION CHEMISTRY REVIEWS 372(2018):101-116. |
入库方式： OAI收割
来源：化学研究所
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