Carbocyclic-fused N,N,N-pincer ligands as ring-strain adjustable supports for iron and cobalt catalysts in ethylene oligo-/polymerization
文献类型：期刊论文
| 作者 | Wang, Z; Solan, GA; Zhang, WJ; Sun, WH
|
| 刊名 | COORDINATION CHEMISTRY REVIEWS
 |
| 出版日期 | 2018-05-15 |
| 卷号 | 363页码:92-108 |
| 关键词 | Iron/cobalt catalysts N,N,N-Pincer ligands Ethylene oligo-/polymerization Bis(arylimino)pyridine Imino-phenanthroline alpha-Olefins Fused units Vinyl-polyethylenes Functional polymers |
| ISSN号 | 0010-8545 |
| DOI | 10.1016/j.ccr.2018.02.016 |
| 英文摘要 | Recent progress in the application of homogeneous iron and cobalt catalysts in ethylene oligo-/ polymerization is reviewed with particular emphasis placed on the tuning of catalyst performance through the introduction of controlled amounts of ring strain to the ligand frame. While new examples of catalysts beating the prototypical bis(arylimino)pyridine continue to emerge in the literature, the last decade has witnessed a number of key advances concerned with the fusion of carbocyclic units to the N,N, N-pincer manifold with a view to enhancing both the catalytic activities and thermal stablility of their resultant catalysts. Some notable examples include iron complexes containing aryl-fused imino-phenanthroline ligands, which have proved highly active catalysts for ethylene oligomerization and indeed have shown considerable industrial promise on the pilot plant scale. Elsewhere, bis(arylimino) pyridines incorporating singly or doubly fused cycloalkyl units with the ring sizes anywhere between five- and eight-membered have been systematically developed and have proved versatile supports for both metal centers. More significantly, clear correlations between structure and activity as well as oligo-/polymer properties are a feature of these strain-adjustable catalysts. In many cases, linear vinyl-polyethylenes are accessible which are in demand for the production of long-chain branched copolymers, functional polymers as well as coating materials. (C) 2018 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000430764400006 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/41972]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Solan, GA 2.Zhang, WJ 3.Sun, WH (reprint author), Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China. 4.Solan, GA 5.Zhang, WJ 6.Sun, WH (reprint author), Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Wang, Z,Solan, GA,Zhang, WJ,et al. Carbocyclic-fused N,N,N-pincer ligands as ring-strain adjustable supports for iron and cobalt catalysts in ethylene oligo-/polymerization[J]. COORDINATION CHEMISTRY REVIEWS,2018,363:92-108. |
| APA | Wang, Z,Solan, GA,Zhang, WJ,&Sun, WH.(2018).Carbocyclic-fused N,N,N-pincer ligands as ring-strain adjustable supports for iron and cobalt catalysts in ethylene oligo-/polymerization.COORDINATION CHEMISTRY REVIEWS,363,92-108. |
| MLA | Wang, Z,et al."Carbocyclic-fused N,N,N-pincer ligands as ring-strain adjustable supports for iron and cobalt catalysts in ethylene oligo-/polymerization".COORDINATION CHEMISTRY REVIEWS 363(2018):92-108. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。