Tridentate Titanium Precatalysts Toward Olefin Polymerization
文献类型：期刊论文
| 作者 | Yuan, SF; Wang, LJ; Zhang, QY; Sun, WH
|
| 刊名 | PROGRESS IN CHEMISTRY
 |
| 出版日期 | 2017-12-01 |
| 卷号 | 29期号:12页码:1462-1470 |
| 关键词 | olefin polymerization titanium complex tridentate ligand catalytic performance |
| ISSN号 | 1005-281X |
| DOI | 10.7536/PC170742 |
| 英文摘要 | Titanium-based catalysts have been not only providing major catalyses in conventionally producing massive polyolefins with low cost as well as good properties, but also advancing the properties of new polyolefins for new plastic materials. Therefore it has been a core consideration of finely tuning the structures of titanium complexes and enhancing catalytic performances of the olefin polymerization. Besides metallocene catalysts, titanium complexes bearing multi-dentate ligands have been maintained as hot topics, in which tridentate ligands positively stabilize titanium complexes. Meanwhile variations of coordination atoms of those ligands greatly enrich the syntheses and manipulation of the catalytic activity of complexes, therefore controlling the polymerization activity as well as improving the microstructures and properties of resultant polyolefin materials. Herein the recent progress of titanium complexes bearing tridentate ligands have been reviewed toward olefin polymerization, focusing on the electronic and steric influences of substituents within ligands on their catalytic activities and properties of resultant polyolefins. The observations would be helpful to design titanium complexes and correlations between activities of complexes and structures of ligands used. |
| 语种 | 中文 |
| WOS记录号 | WOS:000425930900003 |
| 出版者 | CHINESE ACAD SCIENCES |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/41978]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | 1.Yuan, SF (reprint author), Shanxi Univ, Inst Appl Chem, Taiyuan 030006, Shanxi, Peoples R China. 2.Yuan, SF (reprint author), Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Shanxi, Peoples R China. 3.Yuan, SF 4.Sun, WH (reprint author), Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Yuan, SF,Wang, LJ,Zhang, QY,et al. Tridentate Titanium Precatalysts Toward Olefin Polymerization[J]. PROGRESS IN CHEMISTRY,2017,29(12):1462-1470. |
| APA | Yuan, SF,Wang, LJ,Zhang, QY,&Sun, WH.(2017).Tridentate Titanium Precatalysts Toward Olefin Polymerization.PROGRESS IN CHEMISTRY,29(12),1462-1470. |
| MLA | Yuan, SF,et al."Tridentate Titanium Precatalysts Toward Olefin Polymerization".PROGRESS IN CHEMISTRY 29.12(2017):1462-1470. |
入库方式： OAI收割
来源：化学研究所
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