Enhancing the Activity and Thermal Stability of Nickel Complex Precatalysts Using 1-[2,6-Bis(bis(4-fluorophenyl)methyl)-4-methyl phenylimino]-2-aryliminoacenaphthylene Derivatives
文献类型：期刊论文
| 作者 | Du, SZ; Kong, SL; Shi, QS; Mao, J; Guo, CY; Yi, JJ; Liang, TL; Sun, WH
|
| 刊名 | ORGANOMETALLICS
 |
| 出版日期 | 2015-02-09 |
| 卷号 | 34期号:3页码:582-590 |
| ISSN号 | 0276-7333 |
| DOI | 10.1021/om500943u |
| 英文摘要 | The series of acenaphthylene-1-[2,6-bis(bis(4-fluorophenyl)methyl)-4-methylphenylimino]-2-arylimine derivatives and their dichloronickel complexes were synthesized and fully characterized as well as the single-crystal X-ray diffraction of representative nickel complexes, revealing a distorted tetrahedral geometry. Upon activation with either MAO or Et2AlCl, all nickel complexes showed high activities in ethylene polymerization; moreover, their catalytic systems showed better thermal stabilities on being manipulated at 80 degrees C as the industrial operating temperature. |
| 语种 | 英语 |
| WOS记录号 | WOS:000349273900008 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/41986]  |
| 专题 | 化学研究所_工程塑料实验室 |
| 作者单位 | Sun, WH (reprint author), Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Du, SZ,Kong, SL,Shi, QS,et al. Enhancing the Activity and Thermal Stability of Nickel Complex Precatalysts Using 1-[2,6-Bis(bis(4-fluorophenyl)methyl)-4-methyl phenylimino]-2-aryliminoacenaphthylene Derivatives[J]. ORGANOMETALLICS,2015,34(3):582-590. |
| APA | Du, SZ.,Kong, SL.,Shi, QS.,Mao, J.,Guo, CY.,...&Sun, WH.(2015).Enhancing the Activity and Thermal Stability of Nickel Complex Precatalysts Using 1-[2,6-Bis(bis(4-fluorophenyl)methyl)-4-methyl phenylimino]-2-aryliminoacenaphthylene Derivatives.ORGANOMETALLICS,34(3),582-590. |
| MLA | Du, SZ,et al."Enhancing the Activity and Thermal Stability of Nickel Complex Precatalysts Using 1-[2,6-Bis(bis(4-fluorophenyl)methyl)-4-methyl phenylimino]-2-aryliminoacenaphthylene Derivatives".ORGANOMETALLICS 34.3(2015):582-590. |
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来源：化学研究所
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