Correlation of Molecular Structure and Charge Transport Properties: A Case Study in Naphthalenediimide-Based Copolymer Semiconductors
文献类型：期刊论文
| 作者 | Hu, Yuanyuan1; Li, Zhaojun2; Jiang, Lang3; Chen, Zhuojun1; Liao, Lei1; Wang, Ergang2 |
| 刊名 | ADVANCED ELECTRONIC MATERIALS
 |
| 出版日期 | 2018-08-01 |
| 卷号 | 4期号:8 |
| ISSN号 | 2199-160X |
| 关键词 | Charge Transport Electron Cloud Overlaps Energetic Disorder Molecular Structures Ofets |
| DOI | 10.1002/aelm.201800203 |
| 英文摘要 | Recent development of donor-acceptor (D-A) structure copolymers has led to the remarkable enhancement of mobility over 10 cm(2) (V s)(-1) in organic semiconductors. Despite these achievements, a thorough understanding of the correlation between molecular structure and charge transport properties is still not achieved. With this goal in mind, the electrical properties of three copolymers based on the naphthalenediimide (NDI) acceptor with different donor units are compared, and the effect of increasing donor length on the electronic structure of semiconductors and the resulting charge transport performance is studied. Structural and morphological characterizations are done to reveal the macro transport properties of the semiconductor films. Then, electrical measurements of the field-effect transistors at variable temperatures are carried out to probe the charge transport property of the semiconductor films. Overall, it is found that the increasing of the donor length from one to three thiophene units would reduce the energetic disorder in the semiconductor films. Meanwhile, the electron cloud overlap between acceptor units would be weakened, which is detrimental to electron transport. Thus, a trading-off between energetic disorder and electron cloud overlap is critical for achieving high mobility in this NDI-based copolymer system. |
| 语种 | 英语 |
| 出版者 | WILEY |
| WOS记录号 | WOS:000441125200023 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/41930]  |
| 专题 | 化学研究所_有机固体实验室 |
| 通讯作者 | Hu, Yuanyuan; Liao, Lei; Wang, Ergang |
| 作者单位 | 1.Hunan Univ, Sch Phys & Elect, Minist Educ, Key Lab Micronano Optoelect Devices, Changsha 410082, Hunan, Peoples R China 2.Chalmers Univ Technol, Dept Chem & Chem Engn, SE-41296 Gothenburg, Sweden 3.Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Yuanyuan,Li, Zhaojun,Jiang, Lang,et al. Correlation of Molecular Structure and Charge Transport Properties: A Case Study in Naphthalenediimide-Based Copolymer Semiconductors[J]. ADVANCED ELECTRONIC MATERIALS,2018,4(8). |
| APA | Hu, Yuanyuan,Li, Zhaojun,Jiang, Lang,Chen, Zhuojun,Liao, Lei,&Wang, Ergang.(2018).Correlation of Molecular Structure and Charge Transport Properties: A Case Study in Naphthalenediimide-Based Copolymer Semiconductors.ADVANCED ELECTRONIC MATERIALS,4(8). |
| MLA | Hu, Yuanyuan,et al."Correlation of Molecular Structure and Charge Transport Properties: A Case Study in Naphthalenediimide-Based Copolymer Semiconductors".ADVANCED ELECTRONIC MATERIALS 4.8(2018). |
入库方式： OAI收割
来源：化学研究所
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