A Layered-Tunnel Intergrowth Structure for High-Performance Sodium-Ion Oxide Cathode
文献类型:期刊论文
作者 | Xiao, Yao1,2; Wang, Peng-Fei1,3; Yin, Ya-Xia1,3; Zhu, Yan-Fang2,4; Yang, Xinan5; Zhang, Xu-Dong1,3; Wang, Yuesheng5; Guo, Xiao-Dong2,4; Zhong, Ben-He2; Guo, Yu-Guo1,3![]() |
刊名 | ADVANCED ENERGY MATERIALS
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出版日期 | 2018-08-06 |
卷号 | 8期号:22 |
关键词 | Cathodes Electrochemistry Layered Oxides Sodium-ion Batteries Tunnel |
ISSN号 | 1614-6832 |
DOI | 10.1002/aenm.201800492 |
英文摘要 | Delivery of high-energy density with long cycle life is facing a severe challenge in developing cathode materials for rechargeable sodium-ion batteries (SIBs). Here a composite Na0.6MnO2 with layered-tunnel structure combining intergrowth morphology of nanoplates and nanorods for SIBs, which is clearly confirmed by micro scanning electron microscopy, high-resolution transmission electron microscopy as well as scanning transmission electron microscopy with atomic resolution is presented. Owing to the integrated advantages of P2 layered structure with high capacity and that of the tunnel structure with excellent cycling stability and superior rate performance, the composite electrode delivers a reversible discharge capacity of 198.2 mAh g(-1) at 0.2C rate, leading to a high-energy density of 520.4 Wh kg(-1). This intergrowth integration engineering strategy may modulate the physical and chemical properties in oxide cathodes and provide new perspectives on the optimal design of high-energy density and high-stable materials for SIBs. |
语种 | 英语 |
WOS记录号 | WOS:000440805400012 |
出版者 | WILEY-V C H VERLAG GMBH |
源URL | [http://ir.iccas.ac.cn/handle/121111/41922] ![]() |
专题 | 化学研究所_分子纳米结构与纳米技术实验室 |
通讯作者 | Guo, Xiao-Dong; Guo, Yu-Guo |
作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Nanostruct & Nanotechnol, CAS Res Educ Ctr Excellence Mol Sci, Beijing 100190, Peoples R China 2.Sichuan Univ, Coll Chem Engn, Chengdu 610065, Sichuan, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia 5.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Xiao, Yao,Wang, Peng-Fei,Yin, Ya-Xia,et al. A Layered-Tunnel Intergrowth Structure for High-Performance Sodium-Ion Oxide Cathode[J]. ADVANCED ENERGY MATERIALS,2018,8(22). |
APA | Xiao, Yao.,Wang, Peng-Fei.,Yin, Ya-Xia.,Zhu, Yan-Fang.,Yang, Xinan.,...&Guo, Yu-Guo.(2018).A Layered-Tunnel Intergrowth Structure for High-Performance Sodium-Ion Oxide Cathode.ADVANCED ENERGY MATERIALS,8(22). |
MLA | Xiao, Yao,et al."A Layered-Tunnel Intergrowth Structure for High-Performance Sodium-Ion Oxide Cathode".ADVANCED ENERGY MATERIALS 8.22(2018). |
入库方式: OAI收割
来源:化学研究所
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