Self-assembly of high-index faceted gold nanocrystals to fabricate tunable coupled plasmonic superlattices
文献类型:期刊论文
作者 | Zhang, Haibin; Guan, Chunlin; Song, Ning; Zhang, Yuanyuan; Liu, Hong; Fang, Jingzhong |
刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS |
出版日期 | 2018-02-07 |
卷号 | 20期号:5页码:3571-3580 |
ISSN号 | 1463-9076 |
DOI | 10.1039/c7cp07112d |
文献子类 | J |
英文摘要 | Herein, we present an effective bottom-up strategy to fabricate unprecedented macroscopic two-dimensional (2D) plasmonic gold superlattices composed of high-index faceted gold nanocrystal building blocks (NBBs) at the air-liquid interface. In this approach, a synergistic electrostatic and layered self-assembly technique was executed using unique icosidodecahedral gold nanocrystals. It showed that centimeter-squared areas of close-packed monolayer films were formed, and the interparticle spacing of neighbouring Au NBBs could be facilely manipulated from hundreds to several nanometers. Optical characterization demonstrated that particular plasmonic coupling could occur and enhance in a wide spectral range (visible and near-IR) as the self-assembled Au superlattices were tuned for an appropriate gap distance and specific NBB size; however, the orientation of individual NBBs remained somewhat unorganized. Thus, the well pronounced shift of localized surface plasmon resonances (LSPR) and the in-depth resonance splitting behaviors were presented in our investigations. Furthermore, corresponding electromagnetic simulations showed good agreement with the experimental results; this indicated that a new class of tunable coupled plasmonic Au superlattices was realized. This study complements the insights into the plasmonic coupling of layered Au superlattices and enables the colloidal self-assembly to extend to unconventional NBBs; thus, it may facilitate the design of novel plasmonic metamaterials or other superstructures for desired functionalities and applications in the future. |
WOS关键词 | NANOPARTICLE SUPERLATTICES ; OPTICAL METAMATERIALS ; ARRAYS ; NANOSTRUCTURES ; RESONANCES ; CLUSTERS ; SIZE |
语种 | 英语 |
WOS记录号 | WOS:000423897900066 |
源URL | [http://ir.ioe.ac.cn/handle/181551/9359] |
专题 | 光电技术研究所_轻量化中心 |
推荐引用方式 GB/T 7714 | Zhang, Haibin,Guan, Chunlin,Song, Ning,et al. Self-assembly of high-index faceted gold nanocrystals to fabricate tunable coupled plasmonic superlattices[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2018,20(5):3571-3580. |
APA | Zhang, Haibin,Guan, Chunlin,Song, Ning,Zhang, Yuanyuan,Liu, Hong,&Fang, Jingzhong.(2018).Self-assembly of high-index faceted gold nanocrystals to fabricate tunable coupled plasmonic superlattices.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,20(5),3571-3580. |
MLA | Zhang, Haibin,et al."Self-assembly of high-index faceted gold nanocrystals to fabricate tunable coupled plasmonic superlattices".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 20.5(2018):3571-3580. |
入库方式: OAI收割
来源:光电技术研究所
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