One-step synthesis of hybrid zeolite with exceptional hydrophobicity to accelerate the interfacial reaction at low temperature
文献类型：期刊论文
| 作者 | Xia, Qinghua3,4; He, Hongqing1; Lu, Xinhuan3,4; Xia, Yongde2; Zhou, Dan3,4; Wu, Zhonghan3,4; Li, Dan3,4 |
| 刊名 | MICROPOROUS AND MESOPOROUS MATERIALS
 |
| 出版日期 | 2019-05-15 |
| 卷号 | 280页码:195-202 |
| 关键词 | Organic-inorganic hybrid zeolite Hydrophobic material Rota-DGC One-step synthesis Phenol hydrogenation |
| ISSN号 | 1387-1811 |
| DOI | 10.1016/j.micromeso.2019.02.002 |
| 英文摘要 | Up to date, hydrophobic hybrid zeolites (water contact angle > 120 degrees) unexceptionally are prepared through post synthesis methods by using long-alkyl-chain organosilanes (C8 similar to C16) as organic Si source. In this work, organic-inorganic hybrid zeolite with exceptional hydrophobicity (WCA of 150 degrees) has been firstly one-step synthesized by rotating dry gel conversion (rota-DGC) route in the present of short-alkyl-chain organosilanes (di-methyldiethoxysilane) without using any structure-directing agents. Not only the efficient utilization for carbon source has been achieved, but also the crystallization rate of hybrid zeolite has been fastened. Various analysis results and hydrophobic stability support the incorporation of Si(CH3)(2) moiety into the zeolite framework. Thus synthesized hybrid zeolite acts as excellent catalyst support for the phenol hydrogenation in aqueous medium at low temperature of 318 K. The hydrophobic/lipophilic property of the catalyst plays an important role in the formation of stable oil/water microenvironment on the surface of catalyst to accelerate the interfacial reactions, and the solubility difference of product and reactant at low temperature in water has promoted the complete conversion of reactant phenol and the high selectivity of cyclohexanol. |
| WOS关键词 | ORGANIC-INORGANIC HYBRID ; HIGHLY SELECTIVE HYDROGENATION ; CATALYSTS ; CARBON ; PHENOL |
| 资助项目 | National Natural Science Foundation of China[21571055] ; National Natural Science Foundation of China[21673069] ; National Natural Science Foundation of China[21503074] ; Hubei Province Outstanding Youth Foundation[2016CFA040] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000462419400023 |
| 出版者 | ELSEVIER SCIENCE BV |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; Hubei Province Outstanding Youth Foundation ; Hubei Province Outstanding Youth Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Hubei Province Outstanding Youth Foundation ; Hubei Province Outstanding Youth Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Hubei Province Outstanding Youth Foundation ; Hubei Province Outstanding Youth Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Hubei Province Outstanding Youth Foundation ; Hubei Province Outstanding Youth Foundation |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/13886]  |
| 专题 | 中国科学院武汉物理与数学研究所 |
| 通讯作者 | Xia, Qinghua; Zhou, Dan |
| 作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan 430071, Hubei, Peoples R China 2.Univ Exeter, Coll Engn Math & Phys Sci, Exeter EX4 4QF, Devon, England 3.Hubei Univ, Minist Educ, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Hubei, Peoples R China 4.Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Wuhan 430062, Hubei, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xia, Qinghua,He, Hongqing,Lu, Xinhuan,et al. One-step synthesis of hybrid zeolite with exceptional hydrophobicity to accelerate the interfacial reaction at low temperature[J]. MICROPOROUS AND MESOPOROUS MATERIALS,2019,280:195-202. |
| APA | Xia, Qinghua.,He, Hongqing.,Lu, Xinhuan.,Xia, Yongde.,Zhou, Dan.,...&Li, Dan.(2019).One-step synthesis of hybrid zeolite with exceptional hydrophobicity to accelerate the interfacial reaction at low temperature.MICROPOROUS AND MESOPOROUS MATERIALS,280,195-202. |
| MLA | Xia, Qinghua,et al."One-step synthesis of hybrid zeolite with exceptional hydrophobicity to accelerate the interfacial reaction at low temperature".MICROPOROUS AND MESOPOROUS MATERIALS 280(2019):195-202. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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