Mass-analyzed threshold ionization spectroscopy of trans-o-methylanisole
文献类型：期刊论文
| 作者 | Tzeng, Wen-Bih3; Zhang, Bing2; Tzeng, Sheng-Yuan3; Qin, Chen1,2,3 |
| 刊名 | JOURNAL OF MOLECULAR SPECTROSCOPY
 |
| 出版日期 | 2019 |
| 卷号 | 355页码:26-31 |
| 关键词 | o-Methylanisole Resonant two-photon ionization Vibronic spectrum Mass-analyzed threshold ionization Cation spectrum |
| ISSN号 | 0022-2852 |
| DOI | 10.1016/j.jms.2018.11.016 |
| 英文摘要 | In this study, we recorded the vibronic and cation spectra of trans-o-methylanisole by using resonant two-photon ionization and mass-analyzed threshold ionization techniques. The excitation energy of the S-1 <- S-0 transition and the adiabatic ionization energy were measured as 36,364 +/- 2 cm(-1) and 64,755 +/- 5 cm(-1), respectively. The red shifts of these values with respect to those of anisole and toluene indicated that the interactions of CH3 and OCH3 substituents with the ring are stronger in the electronically excited S-1 and cationic ground Do states than that in the electronically ground S o state. Most of the observed bands in the S-1 and D-0 states involve in-plane ring deformation and methyl internal rotation. The vibrational frequencies of modes 6b(1), 6a(l), and 1(1) were lower in the S-1 state than in the D-0 state. This suggested that trans-o-methylanisole is more rigid in the D-0 state than in the S-1 state. (C) 2018 Elsevier Inc. All rights reserved. |
| WOS关键词 | RESONANT 2-PHOTON IONIZATION ; MOLECULAR-ORBITAL METHODS ; ELECTRONIC-TRANSITION ; MATI SPECTROSCOPY ; P-FLUOROANILINE ; BASIS-SETS ; ROTAMERS ; CATIONS ; ENERGY ; S-1 |
| 资助项目 | Ministry of Science and Technology of the Republic of China[MOST-107-2113-M-001-014] ; Natural Science Foundation of Xinjiang Uygur Autonomous Region[2016D01A058] |
| WOS研究方向 | Physics ; Spectroscopy |
| 语种 | 英语 |
| WOS记录号 | WOS:000456637300005 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 资助机构 | Ministry of Science and Technology of the Republic of China ; Ministry of Science and Technology of the Republic of China ; Natural Science Foundation of Xinjiang Uygur Autonomous Region ; Natural Science Foundation of Xinjiang Uygur Autonomous Region ; Ministry of Science and Technology of the Republic of China ; Ministry of Science and Technology of the Republic of China ; Natural Science Foundation of Xinjiang Uygur Autonomous Region ; Natural Science Foundation of Xinjiang Uygur Autonomous Region ; Ministry of Science and Technology of the Republic of China ; Ministry of Science and Technology of the Republic of China ; Natural Science Foundation of Xinjiang Uygur Autonomous Region ; Natural Science Foundation of Xinjiang Uygur Autonomous Region ; Ministry of Science and Technology of the Republic of China ; Ministry of Science and Technology of the Republic of China ; Natural Science Foundation of Xinjiang Uygur Autonomous Region ; Natural Science Foundation of Xinjiang Uygur Autonomous Region |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/14135]  |
| 专题 | 中国科学院武汉物理与数学研究所 |
| 通讯作者 | Tzeng, Wen-Bih; Qin, Chen |
| 作者单位 | 1.Xinjiang Normal Univ, Sch Phys & Elect Engn, Key Lab Mineral Luminescent Mat & Microstruct Xin, Urumqi 830054, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China 3.Acad Sinica, Inst Atom & Mol Sci, Lab Mass Spectrometr & Spectroscop Studies Biomol, Taipei 10617, Taiwan |
| 推荐引用方式 GB/T 7714 | Tzeng, Wen-Bih,Zhang, Bing,Tzeng, Sheng-Yuan,et al. Mass-analyzed threshold ionization spectroscopy of trans-o-methylanisole[J]. JOURNAL OF MOLECULAR SPECTROSCOPY,2019,355:26-31. |
| APA | Tzeng, Wen-Bih,Zhang, Bing,Tzeng, Sheng-Yuan,&Qin, Chen.(2019).Mass-analyzed threshold ionization spectroscopy of trans-o-methylanisole.JOURNAL OF MOLECULAR SPECTROSCOPY,355,26-31. |
| MLA | Tzeng, Wen-Bih,et al."Mass-analyzed threshold ionization spectroscopy of trans-o-methylanisole".JOURNAL OF MOLECULAR SPECTROSCOPY 355(2019):26-31. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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