Ultrafast spectroscopy of the primary charge transfer and ISC processes in 9-anthraldehyde
文献类型：期刊论文
| 作者 | Zhang, Bing2; Zhang, Song2; Wang, Lian; Zhou, Miaomiao |
| 刊名 | CHEMICAL PHYSICS LETTERS
 |
| 出版日期 | 2019-02-16 |
| 卷号 | 717页码:1-6 |
| 关键词 | Time-resolved transient absorption spectroscopy Intramolecular charge transfer Radiationless intersystem crossing |
| ISSN号 | 0009-2614 |
| DOI | 10.1016/j.cplett.2018.12.040 |
| 英文摘要 | The ultrafast charge transfer (CT) and the following intersystem crossing (ISC) processes of 9-anthraldehyde were investigated in ethanol and hexane using femtosecond transient absorption spectroscopy combined with quantum chemical calculations. The CT was observed within 0.11 ps in ethanol and 0.23 ps in hexane. Due to the stronger polarity in ethanol, the CT is faster than in hexane. The following ISC is determined to be 22.3 ps and 21.4 ps in two solvents, respectively. However, the timescales of ISC are similar in both solvents since the excited energies of the S-1 and triplet states are close. |
| WOS关键词 | EXCITED-STATE DYNAMICS ; ELECTRON-TRANSFER ; PHOTOCHEMICAL PROPERTIES ; DNA ; TRANSPORT ; COMPLEX ; OXYGEN |
| 资助项目 | National Natural Science Foundation of China[11674355] ; National Natural Science Foundation of China[21327804] ; National Natural Science Foundation of China[21573279] ; National Natural Science Foundation of China[11574351] ; National Natural Science Foundation of China[21773299] |
| WOS研究方向 | Chemistry ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000457867100001 |
| 出版者 | ELSEVIER SCIENCE BV |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/14347]  |
| 专题 | 中国科学院武汉物理与数学研究所 |
| 通讯作者 | Zhang, Bing; Zhang, Song |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Bing,Zhang, Song,Wang, Lian,et al. Ultrafast spectroscopy of the primary charge transfer and ISC processes in 9-anthraldehyde[J]. CHEMICAL PHYSICS LETTERS,2019,717:1-6. |
| APA | Zhang, Bing,Zhang, Song,Wang, Lian,&Zhou, Miaomiao.(2019).Ultrafast spectroscopy of the primary charge transfer and ISC processes in 9-anthraldehyde.CHEMICAL PHYSICS LETTERS,717,1-6. |
| MLA | Zhang, Bing,et al."Ultrafast spectroscopy of the primary charge transfer and ISC processes in 9-anthraldehyde".CHEMICAL PHYSICS LETTERS 717(2019):1-6. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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