Enhanced catalytic performance for CO preferential oxidation over CuO catalysts supported on highly defective CeO2 nanocrystals
文献类型：期刊论文
| 作者 | Ma, K; Zhang J(张静) ; Zheng LR(郑黎荣); Li, XG; Zhang, J; Zheng, LR; Ding, T; Tian, Y; Tan, SR; Bai, XQ
|
| 刊名 | APPLIED SURFACE SCIENCE
 |
| 出版日期 | 2017 |
| 卷号 | 422页码:932-943 |
| 关键词 | CuO/CeO2 catalysts CO PROX Ce(OH)(3) nanowires CeO2 nanocrystals |
| ISSN号 | 0169-4332 |
| DOI | 10.1016/j.apsusc.2017.06.017 |
| 文献子类 | Article |
| 英文摘要 | Herein, we synthesized CeO2 nanocrystals (Ce250) with a large number of surface lattice defects by calcining the superfine Ce(OH)(3) nanowires at 250 degrees C. They were then utilized as the support of the CuO catalysts for CO preferential oxidation (CO PROX). The strong interaction between CuO and CeO2 is the key factor to improve the catalytic activity, and our results show that the surface lattice defects on the CeO2 support can strengthen the interaction between CuO and CeO2 during the catalyst preparation procedure. With the increase of the calcination temperature, the surface areas of the CuO/CeO2 catalysts gradually drops, but the interaction between CuO and CeO2 is strengthened. Their catalytic activities present a "volcano" type, and the CuCe500 calcined at 500 degrees C shows the highest catalytic activity. (C) 2017 Elsevier B.V. All rights reserved. |
| 电子版国际标准刊号 | 1873-5584 |
| WOS关键词 | GAS SHIFT REACTION ; SELECTIVE OXIDATION ; CUO-CEO2 CATALYSTS ; CARBON-MONOXIDE ; H-2-RICH STREAM ; NO REDUCTION ; IN-SITU ; THERMAL-DECOMPOSITION ; EXCESS HYDROGEN ; LOW-TEMPERATURE |
| WOS研究方向 | Chemistry ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000410606900110 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/284730]  |
| 专题 | 高能物理研究所_多学科研究中心 高能物理研究所_实验物理中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Ma, K,Zhang J,Zheng LR,et al. Enhanced catalytic performance for CO preferential oxidation over CuO catalysts supported on highly defective CeO2 nanocrystals[J]. APPLIED SURFACE SCIENCE,2017,422:932-943. |
| APA | Ma, K.,张静.,郑黎荣.,Li, XG.,Zhang, J.,...&Wang, XL.(2017).Enhanced catalytic performance for CO preferential oxidation over CuO catalysts supported on highly defective CeO2 nanocrystals.APPLIED SURFACE SCIENCE,422,932-943. |
| MLA | Ma, K,et al."Enhanced catalytic performance for CO preferential oxidation over CuO catalysts supported on highly defective CeO2 nanocrystals".APPLIED SURFACE SCIENCE 422(2017):932-943. |
入库方式： OAI收割
来源：高能物理研究所
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