Activating cobalt(II) oxide nanorods for efficient electrocatalysis by strain engineering
文献类型：期刊论文
| 作者 | Zheng, Lirong ; Mao, Jing; Liu, Hui; Du, Xi-Wen; Zheng LR(郑黎荣); Qiao, Shi-Zhang; Jaroniec, Mietek; Yan, Dong-Yang; Ling, Tao; Wang, Hui
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| 刊名 | NATURE COMMUNICATIONS
 |
| 出版日期 | 2017 |
| 卷号 | 8页码:1509 |
| ISSN号 | 2041-1723 |
| DOI | 10.1038/s41467-017-01872-y |
| 文献子类 | Article |
| 英文摘要 | Designing high-performance and cost-effective electrocatalysts toward oxygen evolution and hydrogen evolution reactions in water-alkali electrolyzers is pivotal for large-scale and sustainable hydrogen production. Earth-abundant transition metal oxide-based catalysts are particularly active for oxygen evolution reaction; however, they are generally considered inactive toward hydrogen evolution reaction. Here, we show that strain engineering of the outermost surface of cobalt(II) oxide nanorods can turn them into efficient electrocatalysts for the hydrogen evolution reaction. They are competitive with the best electrocatalysts for this reaction in alkaline media so far. Our theoretical and experimental results demonstrate that the tensile strain strongly couples the atomic, electronic structure properties and the activity of the cobalt(II) oxide surface, which results in the creation of a large quantity of oxygen vacancies that facilitate water dissociation, and fine tunes the electronic structure to weaken hydrogen adsorption toward the optimum region. |
| WOS关键词 | HYDROGEN-EVOLUTION REACTION ; OXYGEN REDUCTION REACTION ; CATION-EXCHANGE ; NANOWIRE ARRAYS ; WATER OXIDATION ; AIR BATTERIES ; CATALYSTS ; NANOSHEETS ; SURFACES ; ENERGY |
| WOS研究方向 | Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:000415262100010 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/284858]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Zheng, Lirong,Mao, Jing,Liu, Hui,et al. Activating cobalt(II) oxide nanorods for efficient electrocatalysis by strain engineering[J]. NATURE COMMUNICATIONS,2017,8:1509. |
| APA | Zheng, Lirong.,Mao, Jing.,Liu, Hui.,Du, Xi-Wen.,郑黎荣.,...&Zheng, Yao.(2017).Activating cobalt(II) oxide nanorods for efficient electrocatalysis by strain engineering.NATURE COMMUNICATIONS,8,1509. |
| MLA | Zheng, Lirong,et al."Activating cobalt(II) oxide nanorods for efficient electrocatalysis by strain engineering".NATURE COMMUNICATIONS 8(2017):1509. |
入库方式： OAI收割
来源：高能物理研究所
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