Interface confined hydrogen evolution reaction in zero valent metal nanoparticles-intercalated molybdenum disulfide
文献类型：期刊论文
| 作者 | Tang, W; Zhao, XX; Leng, K; Chen, ZX ; Zheng LR(郑黎荣); Loh, KP; Yeo, BS; Lin, M; Zheng, LR; Dong, L
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| 刊名 | NATURE COMMUNICATIONS
 |
| 出版日期 | 2017 |
| 卷号 | 8页码:14548 |
| ISSN号 | 2041-1723 |
| DOI | 10.1038/ncomms14548 |
| 文献子类 | Article |
| 英文摘要 | Interface confined reactions, which can modulate the bonding of reactants with catalytic centres and influence the rate of the mass transport from bulk solution, have emerged as a viable strategy for achieving highly stable and selective catalysis. Here we demonstrate that 1T'-enriched lithiated molybdenum disulfide is a highly powerful reducing agent, which can be exploited for the in-situ reduction of metal ions within the inner planes of lithiated molybdenum disulfide to form a zero valent metal-intercalated molybdenum disulfide. The confinement of platinum nanoparticles within the molybdenum disulfide layered structure leads to enhanced hydrogen evolution reaction activity and stability compared to catalysts dispersed on carbon support. In particular, the inner platinum surface is accessible to charged species like proton and metal ions, while blocking poisoning by larger sized pollutants or neutral molecules. This points a way forward for using bulk intercalated compounds for energy related applications. |
| WOS关键词 | X-RAY-DIFFRACTION ; CARBON NANOTUBES ; MOS2 NANOSHEETS ; CATALYSIS ; STABILITY ; OXIDATION ; DICHALCOGENIDE ; CARBIDE ; SURFACE ; ROUTE |
| WOS研究方向 | Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:000394588600001 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/284859]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Tang, W,Zhao, XX,Leng, K,et al. Interface confined hydrogen evolution reaction in zero valent metal nanoparticles-intercalated molybdenum disulfide[J]. NATURE COMMUNICATIONS,2017,8:14548. |
| APA | Tang, W.,Zhao, XX.,Leng, K.,Chen, ZX.,郑黎荣.,...&Malkhandi, S.(2017).Interface confined hydrogen evolution reaction in zero valent metal nanoparticles-intercalated molybdenum disulfide.NATURE COMMUNICATIONS,8,14548. |
| MLA | Tang, W,et al."Interface confined hydrogen evolution reaction in zero valent metal nanoparticles-intercalated molybdenum disulfide".NATURE COMMUNICATIONS 8(2017):14548. |
入库方式： OAI收割
来源：高能物理研究所
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