Solvent-Dependent Synthesis of Porous Anionic Uranyl-Organic Frameworks Featuring a Highly Symmetrical (3,4)-Connected ctn or bor Topology for Selective Dye Adsorption
文献类型：期刊论文
| 作者 | Jiang, X; Hu, KQ; Wang, CZ ; Mei, L; Xie, ZN; Tao, WQ; Zhang, XL; Hu KQ(胡孔球); Zhang XL(张晓琳); Chai, ZF
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| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2017 |
| 卷号 | 23期号:3页码:529-532 |
| 关键词 | interpenetrating structures metal-organic frameworks morphology change selective dye adsorption uranyl cation |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201604225 |
| 文献子类 | Article |
| 英文摘要 | Two highly symmetrical (3,4)-connected uranylorganic frameworks (UOFs) were synthesized by a judicious combination of D-3h-symmetrical triangular [UO2(COO)(3)](-) and T-d symmetrical tetrahedral tetrakis(4-carboxyphenyl)-methane (H4MTB). These two as-synthesized UOFs possess similar structural units and coordination modes but totally different topological structures, namely ctn net and bor net. Solvent-induced interpenetration and a morphology change are observed. The two compounds exhibit crystal transformation via a dissolution-crystallization process. Adsorption experiments in CH3OH solution indicate that both of them can selectively remove positively charged dyes over negatively charged and neutral dyes. Moreover, the electronic structural and bonding properties of the two compounds were systematically explored by density functional theory (DFT) calculations. |
| 电子版国际标准刊号 | 1521-3765 |
| WOS关键词 | COORDINATION POLYMER ; MAGNETIC-PROPERTIES ; HYDROGEN UPTAKE ; SOLID-STATE ; METAL ; NETWORKS ; LUMINESCENCE ; CARBOXYLATES ; TRANSITION ; SEPARATION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000393625600005 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/284936]  |
| 专题 | 高能物理研究所_多学科研究中心 中国科学院高能物理研究所_中国散裂中子源 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Jiang, X,Hu, KQ,Wang, CZ,et al. Solvent-Dependent Synthesis of Porous Anionic Uranyl-Organic Frameworks Featuring a Highly Symmetrical (3,4)-Connected ctn or bor Topology for Selective Dye Adsorption[J]. CHEMISTRY-A EUROPEAN JOURNAL,2017,23(3):529-532. |
| APA | Jiang, X.,Hu, KQ.,Wang, CZ.,Mei, L.,Xie, ZN.,...&石伟群.(2017).Solvent-Dependent Synthesis of Porous Anionic Uranyl-Organic Frameworks Featuring a Highly Symmetrical (3,4)-Connected ctn or bor Topology for Selective Dye Adsorption.CHEMISTRY-A EUROPEAN JOURNAL,23(3),529-532. |
| MLA | Jiang, X,et al."Solvent-Dependent Synthesis of Porous Anionic Uranyl-Organic Frameworks Featuring a Highly Symmetrical (3,4)-Connected ctn or bor Topology for Selective Dye Adsorption".CHEMISTRY-A EUROPEAN JOURNAL 23.3(2017):529-532. |
入库方式： OAI收割
来源：高能物理研究所
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