Synthesis of birnessite with adjustable electron spin magnetic moments for the degradation of tetracycline under microwave induction
文献类型：期刊论文
| ; | |
| 作者 | Lv, GC; Xing, XB; Liao, LB; An, PF ; Yin, H; Mei, LF; Li, ZH; An PF(安鹏飞)
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| 刊名 | CHEMICAL ENGINEERING JOURNAL
 ; CHEMICAL ENGINEERING JOURNAL
|
| 出版日期 | 2017 ; 2017 |
| 卷号 | 326页码:329-338 |
| 关键词 | Birnessite Birnessite Electron spin magnetic moment Microwave Degradation Tetracycline Electron spin magnetic moment Microwave Degradation Tetracycline |
| ISSN号 | 1385-8947 ; 1385-8947 |
| DOI | 10.1016/j.cej.2017.05.123 ; 10.1016/j.cej.2017.05.123 |
| 文献子类 | Article ; Article |
| 英文摘要 | Manganese dioxides (MOs) are excellent microwave absorbing materials and have been used as substrates or catalysts for enhanced degradation of organic compounds. In this study, we extended our research on using birnessite (Birn), a type of MOs, for the degradation of tetracycline (TC) in aqueous solution under microwave induction (MI). The Birns were fabricated to achieve different ratios of Mn (II)/Mn(III)/Mn(IV) in the crystal structure. Their physical and chemical characteristics were determined by X-ray diffraction, field-emission environmental scanning electron microscopy, high-resolution transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray absorption fine structure spectra, and a microwave network analyzer. Their removal of TC under MI was evaluated under different physicochemical conditions. Lower solution pH, higher MI power, and higher Mn(II) and Mn(III) in the structure resulted in more TC removal. And the Birns are regenerable. LC-MS analyses confirmed the presence of degradation intermediates. The better performances of TC removal by Birns under MI was attributed to the high magnetic spin moment of Mn(II) and Mn(III) in the structure that has higher MI response. (C) 2017 Elsevier B.V. All rights reserved.; Manganese dioxides (MOs) are excellent microwave absorbing materials and have been used as substrates or catalysts for enhanced degradation of organic compounds. In this study, we extended our research on using birnessite (Birn), a type of MOs, for the degradation of tetracycline (TC) in aqueous solution under microwave induction (MI). The Birns were fabricated to achieve different ratios of Mn (II)/Mn(III)/Mn(IV) in the crystal structure. Their physical and chemical characteristics were determined by X-ray diffraction, field-emission environmental scanning electron microscopy, high-resolution transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray absorption fine structure spectra, and a microwave network analyzer. Their removal of TC under MI was evaluated under different physicochemical conditions. Lower solution pH, higher MI power, and higher Mn(II) and Mn(III) in the structure resulted in more TC removal. And the Birns are regenerable. LC-MS analyses confirmed the presence of degradation intermediates. The better performances of TC removal by Birns under MI was attributed to the high magnetic spin moment of Mn(II) and Mn(III) in the structure that has higher MI response. (C) 2017 Elsevier B.V. All rights reserved. |
| 电子版国际标准刊号 | 1873-3212 ; 1873-3212 |
| WOS关键词 | MANGANESE-DIOXIDE ; MANGANESE-DIOXIDE ; PHOTOCATALYTIC DEGRADATION ; AQUEOUS-SOLUTION ; P-NITROPHENOL ; MNO2 ; MECHANISM ; REMOVAL ; OXIDE ; TIO2 ; PEROXYMONOSULFATE ; PHOTOCATALYTIC DEGRADATION ; AQUEOUS-SOLUTION ; P-NITROPHENOL ; MNO2 ; MECHANISM ; REMOVAL ; OXIDE ; TIO2 ; PEROXYMONOSULFATE |
| WOS研究方向 | Engineering ; Engineering |
| 语种 | 英语 ; 英语 |
| WOS记录号 | WOS:000406137200034 ; WOS:000406137200034 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/285143]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Lv, GC,Xing, XB,Liao, LB,et al. Synthesis of birnessite with adjustable electron spin magnetic moments for the degradation of tetracycline under microwave induction, Synthesis of birnessite with adjustable electron spin magnetic moments for the degradation of tetracycline under microwave induction[J]. CHEMICAL ENGINEERING JOURNAL, CHEMICAL ENGINEERING JOURNAL,2017, 2017,326, 326:329-338, 329-338. |
| APA | Lv, GC.,Xing, XB.,Liao, LB.,An, PF.,Yin, H.,...&安鹏飞.(2017).Synthesis of birnessite with adjustable electron spin magnetic moments for the degradation of tetracycline under microwave induction.CHEMICAL ENGINEERING JOURNAL,326,329-338. |
| MLA | Lv, GC,et al."Synthesis of birnessite with adjustable electron spin magnetic moments for the degradation of tetracycline under microwave induction".CHEMICAL ENGINEERING JOURNAL 326(2017):329-338. |
入库方式： OAI收割
来源：高能物理研究所
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