Oxidative Esterification of Methacrolein to Methyl Methacrylate over Gold Nanoparticles on Hydroxyapatite
文献类型：期刊论文
| 作者 | Zhang P(张鹏); Gao, J; Li, F; Cao XZ(曹兴忠) ; Zhang, P; Cao, XZ; Yang, L; Fan, GL
|
| 刊名 | CHEMCATCHEM
 |
| 出版日期 | 2017 |
| 卷号 | 9期号:7页码:1230-1241 |
| 关键词 | gold nanoparticles oxidation polymorphism supported catalysts |
| ISSN号 | 1867-3880 |
| DOI | 10.1002/cctc.201601560 |
| 文献子类 | Article |
| 英文摘要 | The catalytic production of methyl methacrylate through the direct oxidative esterification of methacrolein is important in terms of green chemistry and sustainable development. In the present work, Au nanoparticles supported on three needle-like, lamella-like, and rodlike hydroxyapatites were synthesized. We demonstrated that needle-like hydroxyapatite could facilitate the higher dispersion of Au species because of its high specific surface area, and the strong interaction between the Au nanoparticles and the support resulted in the formation of more surface defects because of the existence of partially encapsulated Au particles by the needle-like hydroxyapatite. The surface defects were related closely to the generation of strong basic sites. Compared with the other two materials, the Au supported on the needle-like hydroxyapatite catalyst, which had a large amount of surface acid-base sites, exhibited a much higher catalytic activity and selectivity to methyl methacrylate in the direct oxidative esterification of methacrolein with methanol under mild reaction conditions (i.e., ambient pressure, low reaction temperature of 70 degrees C, and low methanol/aldehyde ratio of 8:1). The superior catalytic performance of the Au supported on needle-like hydroxyapatite catalyst was attributable to a cooperative effect between abundant acid-base sites for the preferential chemisorption of methacrolein and highly dispersed active Au species for the favorable formation of -hydride and oxygen activation. The present findings open a new and promising route for the practical production of methyl methacrylate using high-performance hydroxyapatite-supported metal catalyst systems. |
| 电子版国际标准刊号 | 1867-3899 |
| WOS关键词 | METAL-SUPPORT INTERACTIONS ; EFFICIENT CATALYSTS ; SELECTIVE HYDROGENATION ; HETEROGENEOUS CATALYSTS ; TIO2 NANOCRYSTALS ; AEROBIC OXIDATION ; CO OXIDATION ; LACTIC-ACID ; LEWIS-ACID ; ALCOHOLS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000398859500013 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/285155]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Zhang P,Gao, J,Li, F,et al. Oxidative Esterification of Methacrolein to Methyl Methacrylate over Gold Nanoparticles on Hydroxyapatite[J]. CHEMCATCHEM,2017,9(7):1230-1241. |
| APA | 张鹏.,Gao, J.,Li, F.,曹兴忠.,Zhang, P.,...&Fan, GL.(2017).Oxidative Esterification of Methacrolein to Methyl Methacrylate over Gold Nanoparticles on Hydroxyapatite.CHEMCATCHEM,9(7),1230-1241. |
| MLA | 张鹏,et al."Oxidative Esterification of Methacrolein to Methyl Methacrylate over Gold Nanoparticles on Hydroxyapatite".CHEMCATCHEM 9.7(2017):1230-1241. |
入库方式： OAI收割
来源：高能物理研究所
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