Preparation of ultrathin, robust membranes through reactive layer-by-layer (LbL) assembly for pervaporation dehydration
文献类型：期刊论文
| 作者 | Liu, GH; Jiang, ZY; Chen, C; Hou, LP; Gao, BX; Yang, H ; Wu, H; Pan, FS; Zhang, P; Cao, XZ
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| 刊名 | JOURNAL OF MEMBRANE SCIENCE
 |
| 出版日期 | 2017 |
| 卷号 | 537页码:229-238 |
| 关键词 | Layer-by-layer assembly Polyphenols Covalent bond Ultrathin membranes Pervaporation |
| ISSN号 | 0376-7388 |
| DOI | 10.1016/j.memsci.2017.05.025 |
| 文献子类 | Article |
| 英文摘要 | Fabricating ultrathin membranes with high separation performance and stability remains a great challenge. Tannic acid (TA) is a bio-based polyphenol and can form multifunctional coatings through catechol chemistry. In this study, polyethyleneimine (PEI) and TA were alternatively deposited on hydrolyzed polyacrylonitrile (HPAN) porous membrane via layer-by-layer (LbL) assembly driven by covalent interaction between the amine groups of PEI and polyphenols of TA. The LbL assembly process was verified by the step-wise change of water contact angles. The formation of covalent bond was confirmed by X-ray photoelectron spectroscopy (XPS). The free volume property of the membranes was revealed by the Doppler broadening energy spectra. The resultant membranes possessed ultrathin active layers with thicknesses ranging from 118 to 220 nm. When utilized for pervaporation dehydration of 90 wt% ethanol aqueous solution, the membrane exhibited high separation performance with permeation flux of 1343 g/m(2) h and separation factor of 1012 with 5.5 bilayers and pH 8 at 349 K, arising from the increased hydrophilicity and favorable free volume property. Moreover, the membrane showed favorable long-term stability due to the strong interfacial interactions. |
| 电子版国际标准刊号 | 1873-3123 |
| WOS关键词 | POLYELECTROLYTE MULTILAYER MEMBRANES ; GRAPHENE OXIDE NANOSHEETS ; SEPARATION PERFORMANCE ; CROSS-LINKING ; POLYMER ; MIXTURES ; BIOMINERALIZATION ; FABRICATION ; PERMEATION ; STABILITY |
| WOS研究方向 | Engineering ; Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000402508600022 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/285160]  |
| 专题 | 高能物理研究所_实验物理中心 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Liu, GH,Jiang, ZY,Chen, C,et al. Preparation of ultrathin, robust membranes through reactive layer-by-layer (LbL) assembly for pervaporation dehydration[J]. JOURNAL OF MEMBRANE SCIENCE,2017,537:229-238. |
| APA | Liu, GH.,Jiang, ZY.,Chen, C.,Hou, LP.,Gao, BX.,...&曹兴忠.(2017).Preparation of ultrathin, robust membranes through reactive layer-by-layer (LbL) assembly for pervaporation dehydration.JOURNAL OF MEMBRANE SCIENCE,537,229-238. |
| MLA | Liu, GH,et al."Preparation of ultrathin, robust membranes through reactive layer-by-layer (LbL) assembly for pervaporation dehydration".JOURNAL OF MEMBRANE SCIENCE 537(2017):229-238. |
入库方式： OAI收割
来源：高能物理研究所
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