Metal-like Boronic-Organic Frameworks: A Design and Computation
文献类型：期刊论文
| 作者 | Gao XJ(高雪皎); Gao, XJJ; Gao XF(高兴发) ; Gao, XF
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| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2017 |
| 卷号 | 56期号:5页码:2490-2495 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/acs.inorgchem.6b02639 |
| 文献子类 | Article |
| 英文摘要 | Because of the lack of strong pi-interaction in their bonds connecting building units, most of the metal organic frameworks (MOFs) and covalent-organic frameworks (COFs) achieved so far are insulators or wide-bandgap semiconductors. The design of metal-like frameworks based on known chemical components is a challenge. This work reports that aryl borons can be linked together through isocyanides to form stable and easily accessible low-dimensional boronic-organic frameworks (BOFs). Particularly, the boron atoms in the BOFs behave like transition metals, forming the combined a sigma-donation and pi-backdonation bonds instead of the usual electron-sharing bonds with the isocyanide linkers. This peculiar bonding endows BOFs with semimetal and narrow-bandgap semiconductor features, which are different from MOFs and COFs and may be found to be useful in future nanoelectronics. The results open a door to integrating the knowledge of the donor-acceptor chemistry in the main group into materials science. |
| 电子版国际标准刊号 | 1520-510X |
| WOS关键词 | MAIN-GROUP CHEMISTRY ; GAUSSIAN-BASIS SETS ; COORDINATION CHEMISTRY ; HETEROCYCLIC CARBENES ; STABILIZED DICARBON ; CARBON(0) COMPOUNDS ; DIVALENT CARBON(0) ; TRANSITION-METALS ; PROTON CONDUCTION ; GROUP ELEMENTS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000395847300019 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/285179]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Gao XJ,Gao, XJJ,Gao XF,et al. Metal-like Boronic-Organic Frameworks: A Design and Computation[J]. INORGANIC CHEMISTRY,2017,56(5):2490-2495. |
| APA | 高雪皎,Gao, XJJ,高兴发,&Gao, XF.(2017).Metal-like Boronic-Organic Frameworks: A Design and Computation.INORGANIC CHEMISTRY,56(5),2490-2495. |
| MLA | 高雪皎,et al."Metal-like Boronic-Organic Frameworks: A Design and Computation".INORGANIC CHEMISTRY 56.5(2017):2490-2495. |
入库方式： OAI收割
来源：高能物理研究所
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