Thermodynamics of the Protonation of an Analogue of Glyphosate, N-(phosphonomethyl)-L-proline, in Aqueous Solutions
文献类型：期刊论文
| 作者 | Liu, BJ ; Mu, WJ; Wei, HY; Wang, DQ; Li, XL; Luo, SZ; Wang DQ(王东琪); Li, Q; Yu, QH; Tian, Y
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| 刊名 | JOURNAL OF SOLUTION CHEMISTRY
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| 出版日期 | 2017 |
| 卷号 | 46期号:5页码:1048-1058 |
| 关键词 | Glyphosate N-(phosphonomethyl)-L-proline Protonation |
| ISSN号 | 0095-9782 |
| DOI | 10.1007/s10953-017-0620-0 |
| 文献子类 | Article |
| 英文摘要 | N-(phosphonomethyl)-L-proline is an analogue of glyphosate. The protonation for N-(phosphonomethyl)-L-proline was studied by potentiometry, calorimetry, P-31 NMR spectroscopy and quantum chemical calculations to further understand the protonation process of glyphosate. The results confirmed that the order of successive protonation sites of totally deprotonated N-(phosphonomethyl)-L-proline are a phosphonate oxygen, amino nitrogen, and finally the carboxylate oxygen. The results can improve the understanding of the biological activity of these types of molecules in solution. |
| 电子版国际标准刊号 | 1572-8927 |
| WOS关键词 | TRIFUNCTIONAL PHOSPHONATE ANIONS ; HYDROTHERMAL SYNTHESIS ; CRYSTAL-STRUCTURE ; CARBOXYLATE-PHOSPHONATE ; EQUILIBRIUM-CONSTANTS ; ACID ; MODEL ; NMR ; POTENTIOMETRY ; DISPERSION |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000404328600003 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/285227]  |
| 专题 | 高能物理研究所_多学科研究中心 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Liu, BJ,Mu, WJ,Wei, HY,et al. Thermodynamics of the Protonation of an Analogue of Glyphosate, N-(phosphonomethyl)-L-proline, in Aqueous Solutions[J]. JOURNAL OF SOLUTION CHEMISTRY,2017,46(5):1048-1058. |
| APA | Liu, BJ.,Mu, WJ.,Wei, HY.,Wang, DQ.,Li, XL.,...&Tian, Y.(2017).Thermodynamics of the Protonation of an Analogue of Glyphosate, N-(phosphonomethyl)-L-proline, in Aqueous Solutions.JOURNAL OF SOLUTION CHEMISTRY,46(5),1048-1058. |
| MLA | Liu, BJ,et al."Thermodynamics of the Protonation of an Analogue of Glyphosate, N-(phosphonomethyl)-L-proline, in Aqueous Solutions".JOURNAL OF SOLUTION CHEMISTRY 46.5(2017):1048-1058. |
入库方式： OAI收割
来源：高能物理研究所
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