Two Three-Dimensional Actinide-Silver Heterometallic Coordination Polymers Based on 2,2 '-Bipyridine-3,3 '-dicarboxylic Acid with Helical Chains Containing Dimeric or Trimeric Motifs
文献类型：期刊论文
| 作者 | Chai ZF(柴之芳) ; Zhao R(赵然); Mei L(梅雷); Hu KQ(胡孔球); Wang L(王琳); Shi WQ(石伟群); Zhao, R; Mei, L; Hu, KQ; Shi, WQ
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| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2017 |
| 卷号 | 2017期号:11页码:1472-1477 |
| 关键词 | Heterometallic complexes Carboxylate ligands Helical structures Actinides Silver |
| ISSN号 | 1434-1948 |
| DOI | 10.1002/ejic.201601369 |
| 文献子类 | Article |
| 英文摘要 | Under hydrothermal conditions, two new 3D actinide- silver (An-Ag) heterometallic coordination polymers, namely, [Ag(UO2)(2)(mu(2)-OH)(bpdc)(2)(H2O)(2)](n) (1) and [Ag3Th6(mu(3)-O)(mu(3)-OH)(mu(2)-OH)(6)(bpdc)(6)(NO3)(6)center dot H2O](n) (2, H(2)bpdc = 2,2'-bipyridine- 3,3'-dicarboxylic acid), were assembled through a hardsoft recognition strategy. Compounds 1 and 2 were character-ized by single-crystal X-ray diffraction, powder X-ray diffraction, and infrared spectroscopy. Both compounds are constructed through the bridging of infinite polynuclear An-bpdc chiral helical chains by AgI cations. Compound 2 represents the first ThIVAgI heterometallic coordination polymer. Furthermore, the thermal stability and luminescence properties of 1 were studied. |
| 电子版国际标准刊号 | 1099-0682 |
| WOS关键词 | METAL-ORGANIC FRAMEWORKS ; URANYL-ION COMPLEXES ; CRYSTAL-STRUCTURE ; HYDROTHERMAL SYNTHESIS ; MAGNETIC-PROPERTIES ; POSTSYNTHETIC REARRANGEMENT/METALATION ; BIMETALLIC URANYL ; LIGAND SYNTHESIS ; HYBRID MATERIALS ; 2,2'-BIPYRIDYL-3,3'-DICARBOXYLATE |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000397852200007 |
| 源URL | [http://ir.ihep.ac.cn/handle/311005/285386]  |
| 专题 | 高能物理研究所_多学科研究中心 中国科学院高能物理研究所_中国散裂中子源 |
| 作者单位 | 中国科学院高能物理研究所 |
| 推荐引用方式 GB/T 7714 | Chai ZF,Zhao R,Mei L,et al. Two Three-Dimensional Actinide-Silver Heterometallic Coordination Polymers Based on 2,2 '-Bipyridine-3,3 '-dicarboxylic Acid with Helical Chains Containing Dimeric or Trimeric Motifs[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2017,2017(11):1472-1477. |
| APA | 柴之芳.,赵然.,梅雷.,胡孔球.,王琳.,...&Wang, L.(2017).Two Three-Dimensional Actinide-Silver Heterometallic Coordination Polymers Based on 2,2 '-Bipyridine-3,3 '-dicarboxylic Acid with Helical Chains Containing Dimeric or Trimeric Motifs.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2017(11),1472-1477. |
| MLA | 柴之芳,et al."Two Three-Dimensional Actinide-Silver Heterometallic Coordination Polymers Based on 2,2 '-Bipyridine-3,3 '-dicarboxylic Acid with Helical Chains Containing Dimeric or Trimeric Motifs".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2017.11(2017):1472-1477. |
入库方式： OAI收割
来源：高能物理研究所
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