中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
High-Pressure Phases of a S-Based Compound: Dimethyl Sulfide

文献类型:期刊论文

作者Qin, ZX; Zhan, XZ; Zhang, QM; Zhan XZ(詹晓芝)
刊名JOURNAL OF PHYSICAL CHEMISTRY A
出版日期2017
卷号121期号:32页码:5983-5990
ISSN号1089-5639
DOI10.1021/acs.jpca.7b05194
文献子类Article
英文摘要The high-pressure behavior of dimethyl sulfide was investigated at room temperature by Raman scattering measurements with pressures up to 30.1 GPa. Phase transitions at 1.3, 3.6-5.8, and 17.2 GPa were found and evidenced by the frequency shifts, pressure coefficients, and changes in fwhm of related modes. These phase transitions were suggested to result from the changes in the inter- and intramolecular bonding of the material. Interestingly, the CH3 groups was compelled to be frozen in positions at a relatively low pressure, suggested by the disappearance of the relative modes softening. In addition, the appearance of lattice mode can also be found at a modest pressure, which makes it possible to gain a superiority for this compound to further investigate the superconductivity with high transition temperatures of bulk hydrogen.
WOS关键词HYDROGEN-BONDED SOLIDS ; TORSIONAL SPECTRA ; CRYSTAL-STRUCTURE ; INDUCED METALLIZATION ; POTENTIAL FUNCTION ; INFRARED-SPECTRA ; SULFUR HYDRIDE ; AB-INITIO ; SUPERCONDUCTIVITY ; MOLECULES
WOS研究方向Chemistry ; Physics
语种英语
WOS记录号WOS:000408180000006
源URL[http://ir.ihep.ac.cn/handle/311005/285259]  
专题高能物理研究所_东莞分部
作者单位中国科学院高能物理研究所
推荐引用方式
GB/T 7714
Qin, ZX,Zhan, XZ,Zhang, QM,et al. High-Pressure Phases of a S-Based Compound: Dimethyl Sulfide[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2017,121(32):5983-5990.
APA Qin, ZX,Zhan, XZ,Zhang, QM,&詹晓芝.(2017).High-Pressure Phases of a S-Based Compound: Dimethyl Sulfide.JOURNAL OF PHYSICAL CHEMISTRY A,121(32),5983-5990.
MLA Qin, ZX,et al."High-Pressure Phases of a S-Based Compound: Dimethyl Sulfide".JOURNAL OF PHYSICAL CHEMISTRY A 121.32(2017):5983-5990.

入库方式: OAI收割

来源:高能物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。