中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Electrical conductivity of Alm82Py15Grs3 almandine-rich garnet determined by impedance spectroscopy at high temperatures and high pressures

文献类型:期刊论文

作者Lidong Dai;  Heping Li;  Haiying Hu;  Jianjun Jiang;  Keshi Hui;  Shuangming Shan
刊名Tectonophysics
出版日期2013
卷号608页码:1086-1093
关键词Electrical Conductivity almandine-rich Garnet oxygen Fugacity high Pressure
英文摘要

Under conditions of 1.0 ~ 3.0 GPa, 973 ~ 1273 K and frequency range from 10- 2 to 106 Hz, the electrical conductivity of Fe-rich garnet single crystal is measured by virtue of YJ-3000 t multi-anvil high-pressure apparatus and Solartron-1260 Impedance/Gain-phase Analyzer. A series of solid oxygen buffers including Fe3O4 + Fe2O3, Ni + NiO, Fe + Fe3O4, Fe + FeO and Mo + MoO2 are chosen to control oxygen fugacity. Two branches of impedance spectra are obtained in the complex impedance plane, one (102-106 Hz) showing a semicircular arc originated from the origin in the Nyquist and Bode diagram, another small tail in the low frequency of 10- 2-102 Hz. Experimental results show that with the rise of temperature (T), electrical conductivity (σ) tends to increase, and Log σ and 1/T satisfies the Arrhenius relation. Under control of a Ni + NiO oxygen buffer, with the rise of pressure, electrical conductivity decreases, and the pre-exponential factor also reduces, while the activation enthalpy rises, activation energy and activation volume of charge carriers are determined as 1.29 ± 0.12 eV and 2.01 ± 0.57 cm3/mol, respectively. The dominant electrical conduction mechanism of anhydrous almandine-rich garnet is the Fe2 + → Fe3 + hopping of small polaron. At 3.0 GPa, electrical conductivity of almandine-rich garnet increases with increasing oxygen fugacity. The electrical conductivity of this sample can be represented by the relation Log10σ=2.67±0.05+0.054±0.003×log10fO2+−5446±68T, where fO2 is the oxygen fugacity (bar) and T is the absolute temperature (K). At a typical temperature and pressure in the upper mantle, the influence of oxygen fugacity is substantial.

语种英语
源URL[http://ir.gyig.ac.cn/handle/42920512-1/9421]  
专题地球化学研究所_地球内部物质高温高压实验室
作者单位1.Laboratory for High Temperature and High Pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, Guizhou 550002, China
2.Graduate School of Chinese Academy of Sciences, Beijing 100039, China
推荐引用方式
GB/T 7714
Lidong Dai;Heping Li;Haiying Hu;Jianjun Jiang;Keshi Hui;Shuangming Shan. Electrical conductivity of Alm82Py15Grs3 almandine-rich garnet determined by impedance spectroscopy at high temperatures and high pressures[J]. Tectonophysics,2013,608:1086-1093.
APA Lidong Dai;Heping Li;Haiying Hu;Jianjun Jiang;Keshi Hui;Shuangming Shan.(2013).Electrical conductivity of Alm82Py15Grs3 almandine-rich garnet determined by impedance spectroscopy at high temperatures and high pressures.Tectonophysics,608,1086-1093.
MLA Lidong Dai;Heping Li;Haiying Hu;Jianjun Jiang;Keshi Hui;Shuangming Shan."Electrical conductivity of Alm82Py15Grs3 almandine-rich garnet determined by impedance spectroscopy at high temperatures and high pressures".Tectonophysics 608(2013):1086-1093.

入库方式: OAI收割

来源:地球化学研究所

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