A Direct Quantitative Raman Method for the Measurement of Dissolved Bisulfate in Acid-Sulfate Fluids
文献类型：期刊论文
| 作者 | Xi, Shichuan1,2,3,4 ; Zhang, Xin1,2,3,4; Luan, Zhendong1,2; Du, Zengfeng1,2; Li, Lianfu1,2,4; Wang, Bing1,2,4; Cao, Lei1,2; Lian, Chao1,2; Yan, Jun1,2
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| 刊名 | APPLIED SPECTROSCOPY
 |
| 出版日期 | 2018-08-01 |
| 卷号 | 72期号:8页码:1234-1243 |
| 关键词 | Quantitative analysis acid sulfate bisulfate concentration Raman spectroscopy |
| ISSN号 | 0003-7028 |
| DOI | 10.1177/0003702818773117 |
| 通讯作者 | Zhang, Xin(xzhang@qdio.ac.cn) |
| 英文摘要 | Raman spectroscopy has been applied to the quantitative analysis of the concentration of bisulfate in acid-sulfate fluids at different temperatures. The quantitative analysis method is based on the peak area ratios of HSO4-(v(1)) and H2O(v(2)), where PA(HSO4-/H2O) = [HSO4-] x (0.0066 x T+ 1.3070) at a temperature range of 0-100 degrees C. We found that the molal scattering coefficient of bisulfate increases slightly at the elevated temperature may be due to the changes of fraction of water molecules that are hydrogen-bonded. The method can also be applied to analyze physicochemical parameters of other acid fluids, such as hydrogen phosphate, bicarbonate, etc., and especially to the in situ detection of deep sea acid-sulfate hydrothermal fluids in the future. |
| 资助项目 | National Natural Science Foundation of China[41576104] ; Key Research Program of Frontier Sciences, CAS[QYZDB-SSW-DQC004] ; Strategic Priority Research Program, CAS[XDA11040301] ; Strategic Priority Research Program, CAS[XDA11030301] ; Open Research Project of National Major Science & Technology Infrastructure (RV KEXUE)[NMSTI-KEXUE2017K01] ; NSFC-Shandong Joint Fund for Marine Science Research Centers[U1606401] ; National Key R&D Program of China[2016YFC0302103] ; Taishan Scholar Project Funding[tspd20161007] |
| WOS研究方向 | Instruments & Instrumentation ; Spectroscopy |
| 语种 | 英语 |
| WOS记录号 | WOS:000440337500009 |
| 出版者 | SAGE PUBLICATIONS INC |
| 源URL | [http://ir.qdio.ac.cn/handle/337002/160006]  |
| 专题 | 海洋研究所_海洋地质与环境重点实验室 |
| 通讯作者 | Zhang, Xin |
| 作者单位 | 1.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Geol & Environm, Qingdao, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, Ctr Deep Sea Res, Qingdao, Peoples R China 3.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Geol, Qingdao, Peoples R China 4.Univ Chinese Acad Sci, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xi, Shichuan,Zhang, Xin,Luan, Zhendong,et al. A Direct Quantitative Raman Method for the Measurement of Dissolved Bisulfate in Acid-Sulfate Fluids[J]. APPLIED SPECTROSCOPY,2018,72(8):1234-1243. |
| APA | Xi, Shichuan.,Zhang, Xin.,Luan, Zhendong.,Du, Zengfeng.,Li, Lianfu.,...&Yan, Jun.(2018).A Direct Quantitative Raman Method for the Measurement of Dissolved Bisulfate in Acid-Sulfate Fluids.APPLIED SPECTROSCOPY,72(8),1234-1243. |
| MLA | Xi, Shichuan,et al."A Direct Quantitative Raman Method for the Measurement of Dissolved Bisulfate in Acid-Sulfate Fluids".APPLIED SPECTROSCOPY 72.8(2018):1234-1243. |
入库方式： OAI收割
来源：海洋研究所
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