中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 海洋研究所
  3. 中国科学院海洋研究所
  4. 海洋腐蚀与防护研究发展中心
Strong acid resistance from electrochemical deposition of WO3 on super-hydrophobic CuO-coated copper surface

文献类型：期刊论文

作者Dou, Wenwen1,2,3; Wang, Peng1; Wu, Jiajia1; Gu, Tingyue3; Zhang, Dun1
刊名MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION
出版日期2018-08-01
卷号69期号:8页码:978-984
关键词acid corrosion chemical etching CuO-WO3 electrochemical deposition super-hydrophobic surface
ISSN号0947-5117
DOI10.1002/maco.201709878
通讯作者Gu, Tingyue(gu@ohio.edu) ; Zhang, Dun(zhangdun@qdio.ac.cn)
英文摘要In marine and industrial environments, salts and aggressive contaminants in water may cause corrosion and degradation, including acid corrosion and erosion. Super-hydrophobic (SH) metal oxide films can keep surfaces dry by expelling water droplets. This inhibits corrosion. However, acid rain can dissolve the metal oxide films. Thus, it is necessary to protect SH films against acid erosion. In this work, a WO3 film was added on top of CuO-coated SH copper surface using electrochemical deposition. The composite SH CuO-WO3 film exhibited a strong acid resistance. After 48h immersion in 0.2N sulfuric acid, the film retained its nearly perfect micro-nano structure with a static water contact angle of 160 +/- 2 degrees. After acid erosion, the corrosion rate in a 3.5% (w/w) NaCl solution was tested using potentiodynamic polarization curves. Its corrosion current density was found to be four orders of magnitude lower compared with CuO-coated copper. This kind of acid resistant SH surfaces with much enhanced ability against atmospheric oxygen corrosion in the presence of salty water have potential applications in marine and other industrial environments.
资助项目National Natural Science Foundation of China[41576079] ; Science & Technology Basic Research Program of Qingdao[15-9-1-31-jch] ; Qingdao National Laboratory for Marine Science and Technology[QNLM2016ORP0413] ; Qingdao National Laboratory for Marine Science and Technology[2017ASTCP-ES02] ; China Scholarship Council ; [MS12015119]
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
语种英语
WOS记录号WOS:000440554900002
出版者WILEY-V C H VERLAG GMBH
源URL[http://ir.qdio.ac.cn/handle/337002/159689]  
专题海洋研究所_海洋腐蚀与防护研究发展中心
通讯作者Gu, Tingyue; Zhang, Dun
作者单位1.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, 7 Nanhai Rd, Qingdao 266071, Peoples R China
2.Univ Chinese Acad Sci, 19 Jia Yuquan Rd, Beijing 100039, Peoples R China
3.Ohio Univ, Inst Corros & Multiphase Technol, Dept Chem & Biomol Engn, Athens, OH 45701 USA
推荐引用方式
GB/T 7714		 Dou, Wenwen,Wang, Peng,Wu, Jiajia,et al. Strong acid resistance from electrochemical deposition of WO3 on super-hydrophobic CuO-coated copper surface[J]. MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION,2018,69(8):978-984.
APA Dou, Wenwen,Wang, Peng,Wu, Jiajia,Gu, Tingyue,&Zhang, Dun.(2018).Strong acid resistance from electrochemical deposition of WO3 on super-hydrophobic CuO-coated copper surface.MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION,69(8),978-984.
MLA Dou, Wenwen,et al."Strong acid resistance from electrochemical deposition of WO3 on super-hydrophobic CuO-coated copper surface".MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION 69.8(2018):978-984.

入库方式： OAI收割

来源：海洋研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。