X-ray photoelectron spectroscopy as a probe of the interaction between rhodium acetate and ionic liquids
文献类型：期刊论文
| 作者 | Men, Shuang1,2,3; Jiang, Jing4 |
| 刊名 | CHEMICAL PHYSICS LETTERS
 |
| 出版日期 | 2016-02-16 |
| 卷号 | 646页码:125-129 |
| ISSN号 | 0009-2614 |
| DOI | 10.1016/j.cplett.2016.01.020 |
| 英文摘要 | X-ray photoelectron spectroscopy (XPS) is used as a probe of the interaction between rhodium acetate ([Rh-2(OAc)(4)]) and ionic liquids. Due to the impact of the anion of ionic liquids on the electronic environment of the rhodium centre, the measured Rh 3d binding energies of [Rh-2(OAc)(4)] dissolved in a series of ionic liquids were found to decrease along with the increasing of the basicity of anions. The reduction of Rh(II) to Rh(0) in 1-octyl-3methylimidazolium acetate ([C(8)C(1)Im][OAc]) under UHV condition was monitored by XPS. The intensity of the new formed metallic Rh(0) peak was found increased along with time. The surface enrichment of the new formed Rh(0) species in the system was also concluded. (C) 2016 Elsevier B.V. All rights reserved. |
| WOS研究方向 | Chemistry ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000369968900022 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://210.72.129.5/handle/321005/122465]  |
| 专题 | 中国科学院沈阳应用生态研究所 |
| 通讯作者 | Men, Shuang |
| 作者单位 | 1.Chinese Acad Sci, Inst Appl Ecol, Shenyang 110016, Peoples R China 2.Shenyang Ligong Univ, Sch Mat Sci & Engn, Shenyang 110159, Peoples R China 3.Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England 4.Northeastern Univ, Sch Mech Engn & Automat, Shenyang 110004, Peoples R China |
| 推荐引用方式 GB/T 7714 | Men, Shuang,Jiang, Jing. X-ray photoelectron spectroscopy as a probe of the interaction between rhodium acetate and ionic liquids[J]. CHEMICAL PHYSICS LETTERS,2016,646:125-129. |
| APA | Men, Shuang,&Jiang, Jing.(2016).X-ray photoelectron spectroscopy as a probe of the interaction between rhodium acetate and ionic liquids.CHEMICAL PHYSICS LETTERS,646,125-129. |
| MLA | Men, Shuang,et al."X-ray photoelectron spectroscopy as a probe of the interaction between rhodium acetate and ionic liquids".CHEMICAL PHYSICS LETTERS 646(2016):125-129. |
入库方式： OAI收割
来源：沈阳应用生态研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。