X-ray Photoelectron Spectroscopy of Imidazolium-Based Zwitterions: The Intramolecular Charge-Transfer Effect
文献类型：期刊论文
| 作者 | Men, Shuang1,2; Jin, Yujuan3 |
| 刊名 | RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
 |
| 出版日期 | 2018-11-01 |
| 卷号 | 92期号:11页码:2337-2340 |
| 关键词 | X-ray photoelectron spectroscopy zwitterions charge-transfer effect |
| ISSN号 | 0036-0244 |
| DOI | 10.1134/S0036024418110389 |
| 英文摘要 | We investigate the imidazolium-based zwitterions, 1-butyl-3-methylimidazolium-2-pentafluorophosphate, together with 1-butyl-3-methylimidazolium hexafluorophosphate using X-ray photoelectron spectroscopy. The intramolecular charge-transfer from the negative headgroup to the positive headgroup is revealed in detail. In the case of the zwitterions, due to the intense charge-transfer effect, binding energies of N 1s and C-2 1s are both lower; whilst P 2p is higher, compared to those of 1-butyl-3-methylimidazolium hexafluorophosphate. Such effect is found negligible for F 1s spectra. It is found that F 1s binding energies for the two samples are the same. |
| 资助项目 | National Science Foundation[51503007] ; General project of Science and Technology Research Project of Liaoning Provincial Department of Education[L2015461] ; Liaoning Provincial Foundation of Science and Technology[20170540780] ; China Postdoctoral Science Foundation funded project[2015M571344] ; Beijing Key Laboratory of Quality Evaluation Technology for Hygiene and Safety of Plastics (Beijing Technology and Business University, Beijing, China)[SS201706] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000447676200042 |
| 出版者 | MAIK NAUKA/INTERPERIODICA/SPRINGER |
| 源URL | [http://210.72.129.5/handle/321005/123323]  |
| 专题 | 中国科学院沈阳应用生态研究所 |
| 通讯作者 | Jin, Yujuan |
| 作者单位 | 1.Chinese Acad Sci, Inst Appl Ecol, Shenyang 110016, Liaoning, Peoples R China 2.Shenyang Ligong Univ, Sch Mat Sci & Engn, Shenyang 110159, Liaoning, Peoples R China 3.Beijing Technol & Business Univ, Sch Mat & Mech Engn, Beijing 100048, Peoples R China |
| 推荐引用方式 GB/T 7714 | Men, Shuang,Jin, Yujuan. X-ray Photoelectron Spectroscopy of Imidazolium-Based Zwitterions: The Intramolecular Charge-Transfer Effect[J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A,2018,92(11):2337-2340. |
| APA | Men, Shuang,&Jin, Yujuan.(2018).X-ray Photoelectron Spectroscopy of Imidazolium-Based Zwitterions: The Intramolecular Charge-Transfer Effect.RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A,92(11),2337-2340. |
| MLA | Men, Shuang,et al."X-ray Photoelectron Spectroscopy of Imidazolium-Based Zwitterions: The Intramolecular Charge-Transfer Effect".RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A 92.11(2018):2337-2340. |
入库方式： OAI收割
来源：沈阳应用生态研究所
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