Isobutane/2-Butene Alkylation Reaction Catalyzed by Cu-Modified and Rare Earth X-Type Zeolite
文献类型：期刊论文
| 作者 | Zhang, Honghua1; Xu, Jiakuo1,2; Tang, Hongguo1; Yang, Zhiqiang1; Liu, Ruixia1,2,3; Zhang, Suojiang1,2,3 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2019-06-05 |
| 卷号 | 58期号:22页码:9690-9700 |
| ISSN号 | 0888-5885 |
| DOI | 10.1021/acs.iecr.9b01638 |
| 英文摘要 | Different metal compositions based on metal-ion-modified X-type zeolite in the isobutane/2-butene alkylation reaction were investigated. Bimetallic (rare earth (RE) and Cu) supported zeolites catalysts owned better lifetime and selectivity than those modified by the single metal (La, Ce, or Cu). CuLaX performed best with a 15 h catalytic lifetime obtained after hydrogen activation when the content of copper was 0.197 mmol/g. The possible reason is that the RE X-type catalyst modified with copper ion increases the concentration of strong Bronsted acid sites, which is more favorable for the hydride transfer in the alkylation. Herein, the valence of copper ions is of importance to the alkylation performance. A mechanism was proposed wherein the existence of Cu+ inhibited the progress of the oligomerization reaction and then prolonged the lifetime of the catalyst through decreasing the desorption concentration of 2-butene in the active site. |
| WOS关键词 | ISOBUTANE/BUTENE ALKYLATION ; DEHYDROGENATION ; ENHANCEMENT ; ADSORPTION ; 1-BUTENE ; 2-BUTENE ; CARBONYLATION ; DEACTIVATION ; MECHANISM ; ACIDITY |
| 资助项目 | National Natural Science Foundation of China Petroleum & Chemical Corporation Joint Fund[U1662129] ; Major Program of National Natural Science Foundation of China[21890762] ; One Hundred Talent Program of CAS ; Key Research Program of Frontier Sciences, CAS[QYZDY-SSW-JSCO 11] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000470939000048 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China Petroleum & Chemical Corporation Joint Fund ; Major Program of National Natural Science Foundation of China ; One Hundred Talent Program of CAS ; Key Research Program of Frontier Sciences, CAS |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/29967]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Liu, Ruixia; Zhang, Suojiang |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Beijing Key Lab Ion Liq, Beijing 100190, Peoples R China 2.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Henan, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Honghua,Xu, Jiakuo,Tang, Hongguo,et al. Isobutane/2-Butene Alkylation Reaction Catalyzed by Cu-Modified and Rare Earth X-Type Zeolite[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2019,58(22):9690-9700. |
| APA | Zhang, Honghua,Xu, Jiakuo,Tang, Hongguo,Yang, Zhiqiang,Liu, Ruixia,&Zhang, Suojiang.(2019).Isobutane/2-Butene Alkylation Reaction Catalyzed by Cu-Modified and Rare Earth X-Type Zeolite.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,58(22),9690-9700. |
| MLA | Zhang, Honghua,et al."Isobutane/2-Butene Alkylation Reaction Catalyzed by Cu-Modified and Rare Earth X-Type Zeolite".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 58.22(2019):9690-9700. |
入库方式： OAI收割
来源：过程工程研究所
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