Hollow carbon polyhedra derived from room temperature synthesized iron-based metal-organic frameworks for supercapacitors
文献类型：期刊论文
| 作者 | Zhuang, Jin-Liang1; Liu, Xiang-Yue1; Mao, Hui-Ling1; Wang, Chen1; Cheng, Hu1; Zhang, Yu1; Du, Xuan2; Zhu, Shao-Bin3; Ren, Bin4 |
| 刊名 | JOURNAL OF POWER SOURCES
 |
| 出版日期 | 2019-07-31 |
| 卷号 | 429页码:9-16 |
| 关键词 | Metal-organic frameworks Hollow carbon polyhedron Supercapacitor Graphitization Hierarchical pore |
| ISSN号 | 0378-7753 |
| DOI | 10.1016/j.jpowsour.2019.04.112 |
| 英文摘要 | Metal-organic frameworks (MOFs) derived porous carbons are promising electrode materials in electrochemical energy conversion and storage systems. However, the typical synthetic route of MOFs involving high temperature, organic solvent, massive energy consuming, and laboratory-scale production, hinders the realistic applications of MOFs serving as sacrificial templates for porous carbon. Herein, we demonstrate that highly crystalline MIL-100 (Fe) nanoparticles (MIL: Materials of Institute Lavoisier) can be synthesized in large scale with low cost under mild and green conditions. High-temperature pyrolysis of MIL-100(Fe) under argon atmosphere results in hollow carbon polyhedra (HCPs) featuring high degree of graphitization and hierarchical pore structures. The obtained HCPs are excellent electrode materials for electric double-layer capacitors (EDLCs), and show a specific capacitance of 214 F g(-1) at current density 50 mA g(-1). Moreover, the HCP-based supercapacitors can endure more than 5000 cycles without significant degradation of capacitance. The unique structure of HCPs, including hollow polyhedral shape, hierarchical micro/mesopore structures, and ultrathin layer of highly graphitized carbon shells, endows the superior performance of HCPs based EDLCs with specific capacitance and high rate capability. |
| WOS关键词 | POROUS CARBON ; NANOPOROUS CARBON ; ENERGY-STORAGE ; MIL-100(FE) ; CARBONIZATION ; MICROWAVE ; TEMPLATE ; NANORODS ; TEREPHTHALATE ; DEPOSITION |
| 资助项目 | NSFC[51302264] ; Natural Science Foundation of Guizhou Province[20161413] ; Ministry of Education of Guizhou Province |
| WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000473118100002 |
| 出版者 | ELSEVIER SCIENCE BV |
| 资助机构 | NSFC ; Natural Science Foundation of Guizhou Province ; Ministry of Education of Guizhou Province |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/30289]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Zhuang, Jin-Liang; Du, Xuan |
| 作者单位 | 1.Guizhou Normal Univ, Sch Chem & Mat Sci, Key Lab Funct Mat Chem Guizhou Prov, Guiyang 550001, Guizhou, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydromet Cleaner Prod Technol, Beijing 100190, Peoples R China 3.NanoFCM INC, Xiamen Pioneering Pk Overseas Chinese Scholars, Xiamen 361005, Fujian, Peoples R China 4.Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Fujian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhuang, Jin-Liang,Liu, Xiang-Yue,Mao, Hui-Ling,et al. Hollow carbon polyhedra derived from room temperature synthesized iron-based metal-organic frameworks for supercapacitors[J]. JOURNAL OF POWER SOURCES,2019,429:9-16. |
| APA | Zhuang, Jin-Liang.,Liu, Xiang-Yue.,Mao, Hui-Ling.,Wang, Chen.,Cheng, Hu.,...&Ren, Bin.(2019).Hollow carbon polyhedra derived from room temperature synthesized iron-based metal-organic frameworks for supercapacitors.JOURNAL OF POWER SOURCES,429,9-16. |
| MLA | Zhuang, Jin-Liang,et al."Hollow carbon polyhedra derived from room temperature synthesized iron-based metal-organic frameworks for supercapacitors".JOURNAL OF POWER SOURCES 429(2019):9-16. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。