Deconstructive di-functionalization of unstrained, benzo cyclic amines by C-N bond cleavage using a recyclable tungsten catalyst
文献类型：期刊论文
| 作者 | Zhang, Yujing1,2; Sun, Shuai2; Su, Yijin1; Zhao, Jian2; Li, Yong-Hong2; Han, Bo1,2; Shi, Feng1 |
| 刊名 | ORGANIC & BIOMOLECULAR CHEMISTRY
 |
| 出版日期 | 2019-05-28 |
| 卷号 | 17期号:20页码:4970-4974 |
| ISSN号 | 1477-0520 |
| DOI | 10.1039/c9ob00693a |
| 通讯作者 | Su, Yijin() ; Shi, Feng(fshi@licp.cas.cn) |
| 英文摘要 | With H2WO4 as the catalyst and H2O2 as the oxidant, we herein report a deconstructive difunctionalization of the C-N bond in unstrained, benzo cyclic amines to generate an ester group and nitro group simultaneously. The preliminary mechanistic studies suggested that the corresponding hydroxamic acid is the key intermediate for this transformation. Importantly, with the utilization of this transformation, we achieved an interesting approach for the ring contraction of quinoline to indole, an example of scaffold hopping in a hetero- aromatic system. |
| 收录类别 | SCI |
| WOS关键词 | ASYMMETRIC HYDROGENATION ; BIOLOGICAL EVALUATION ; AEROBIC OXIDATION ; EFFICIENT ; MILD ; TETRAHYDROQUINOLINES ; DEHYDROGENATION ; FLUORINATION ; DERIVATIVES ; CHEMISTRY |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000468790100003 |
| 出版者 | ROYAL SOC CHEMISTRY |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2555440 |
| 专题 | 寒区旱区环境与工程研究所 |
| 通讯作者 | Su, Yijin; Shi, Feng |
| 作者单位 | 1.Chinese Acad Sci, LICP, State Key Lab Oxo Synth & Select Oxidat, 18 Tianshui Middle Rd, Lanzhou, Gansu, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yujing,Sun, Shuai,Su, Yijin,et al. Deconstructive di-functionalization of unstrained, benzo cyclic amines by C-N bond cleavage using a recyclable tungsten catalyst[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2019,17(20):4970-4974. |
| APA | Zhang, Yujing.,Sun, Shuai.,Su, Yijin.,Zhao, Jian.,Li, Yong-Hong.,...&Shi, Feng.(2019).Deconstructive di-functionalization of unstrained, benzo cyclic amines by C-N bond cleavage using a recyclable tungsten catalyst.ORGANIC & BIOMOLECULAR CHEMISTRY,17(20),4970-4974. |
| MLA | Zhang, Yujing,et al."Deconstructive di-functionalization of unstrained, benzo cyclic amines by C-N bond cleavage using a recyclable tungsten catalyst".ORGANIC & BIOMOLECULAR CHEMISTRY 17.20(2019):4970-4974. |
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来源：寒区旱区环境与工程研究所
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