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Prediction of solvents extraction - the organochlorine pesticides in soil using solubility parameter

文献类型:期刊论文

作者Lang, YH; Cao, ZM; Jiang, X
刊名TALANTA
出版日期2005-03-31
卷号66期号:1页码:249-252
关键词solubility parameters soxhlet extraction organic solvents organochlorme pesticides
ISSN号0039-9140
DOI10.1016/j.talanta.2004.11.018
通讯作者Lang, YH(yhlang@ouc.edu.cn)
英文摘要Prediction of the optimal extraction solvent based on the solubility parameter to extract the typical organochlorine pesticides from Jiangxi red soil was reported in this paper. Hildebrand solubility parameters, including dispersion coefficient (delta(d)), polarity (delta(p)) and hydrogen bonding (delta(h)), of extraction solvents (including hexane, dichloromethane, hexane/methanol (4: 1, v/v), hexane/acetone (1: 1, v/v), hexane/dichloromethane (1: 1, v/v) and organochlorine pesticides were calculated using group contribution method. The solvents, such as hexane/methanol (4: 1, v/v) and hexane/acetone (1:1, v/v) were selected as ideal extraction solvents to extract op'-DDT op'-DDE and op'-DDD with high recoveries (> 82%), furthermore, these solvents can be used to extract ce-endosulfan, Endrin and HCB with the reliable recoveries (> 75%). The estimated finding by solubility parameters was supported by the results of soxhlet extraction. (c) 2004 Elsevier B.V. All rights reserved.
收录类别SCI
WOS研究方向Chemistry
WOS类目Chemistry, Analytical
语种英语
WOS记录号WOS:000228686600037
出版者ELSEVIER SCIENCE BV
URI标识http://www.irgrid.ac.cn/handle/1471x/2558457
专题南京土壤研究所
通讯作者Lang, YH
作者单位1.Ocean Univ China, Coll Environm Sci & Engn, Qingdao 266003, Peoples R China
2.Inst Environm Sci, Qingdao 266003, Peoples R China
3.Chinese Acad Sci, Inst Soil Sci, Nanjing 210008, Peoples R China
推荐引用方式
GB/T 7714
Lang, YH,Cao, ZM,Jiang, X. Prediction of solvents extraction - the organochlorine pesticides in soil using solubility parameter[J]. TALANTA,2005,66(1):249-252.
APA Lang, YH,Cao, ZM,&Jiang, X.(2005).Prediction of solvents extraction - the organochlorine pesticides in soil using solubility parameter.TALANTA,66(1),249-252.
MLA Lang, YH,et al."Prediction of solvents extraction - the organochlorine pesticides in soil using solubility parameter".TALANTA 66.1(2005):249-252.

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来源:南京土壤研究所

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