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Effect of low molecular weight organic acids on adsorption and desorption of fluoride on variable charge soils

文献类型:期刊论文

作者Xu, RK; Wang, YY; Zhao, AZ; Ji, GL; Zhang, H
刊名ENVIRONMENTAL GEOCHEMISTRY AND HEALTH
出版日期2006-02-01
卷号28期号:1-2页码:141-146
关键词Al dissolution fluoride Haplic Acrisol organic acids Rhodic Ferralsol
ISSN号0269-4042
DOI10.1007/s10653-005-9023-z
通讯作者Xu, RK(rkxu@issas.ac.cn)
英文摘要The effect of four low molecular weight organic acids on F- adsorption by two variable charge soils was investigated using a batch method. The organic acids reduced F- adsorption through competition by the acids with F- for sorption sites. Oxalic and malonic acids, both of which have simpler chemical structures, were more effective than citric or malic acid. The effect of organic acids on F- adsorption was more prominent at higher pH values and with larger amounts of the organic acids. The desorption study showed that the organic acids enhanced the desorption of F- adsorbed by the soils. In the control and malic acid systems, desorption increased sharply with decreasing pH, while in the oxalic acid system, desorption rose slightly with decreasing pH. Desorption also increased with increasing amount of organic acid added. There are two possible mechanisms for the effect of the organic acids on F- adsorption and desorption: (1) competition of the organic acids with F- for adsorption sites and (2) dissolution of the adsorbents, especially dissolution of soil Al.
收录类别ISTP ; SCI
WOS关键词ALUMINUM ; SORPTION ; ANIONS ; RHIZOSPHERE
WOS研究方向Engineering ; Environmental Sciences & Ecology ; Public, Environmental & Occupational Health ; Water Resources
WOS类目Engineering, Environmental ; Environmental Sciences ; Public, Environmental & Occupational Health ; Water Resources
语种英语
WOS记录号WOS:000237333800019
出版者SPRINGER
URI标识http://www.irgrid.ac.cn/handle/1471x/2558576
专题南京土壤研究所
通讯作者Xu, RK
作者单位1.Chinese Acad Sci, Inst Soil Sci, Nanjing 210008, Peoples R China
2.Tennessee Technol Univ, Dept Chem, Cookeville, TN 38505 USA
推荐引用方式
GB/T 7714
Xu, RK,Wang, YY,Zhao, AZ,et al. Effect of low molecular weight organic acids on adsorption and desorption of fluoride on variable charge soils[J]. ENVIRONMENTAL GEOCHEMISTRY AND HEALTH,2006,28(1-2):141-146.
APA Xu, RK,Wang, YY,Zhao, AZ,Ji, GL,&Zhang, H.(2006).Effect of low molecular weight organic acids on adsorption and desorption of fluoride on variable charge soils.ENVIRONMENTAL GEOCHEMISTRY AND HEALTH,28(1-2),141-146.
MLA Xu, RK,et al."Effect of low molecular weight organic acids on adsorption and desorption of fluoride on variable charge soils".ENVIRONMENTAL GEOCHEMISTRY AND HEALTH 28.1-2(2006):141-146.

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来源:南京土壤研究所

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