In-channel indirect amperometric detection of heavy metal ions for electrophoresis on a poly(dimethylsiloxane) microchip
文献类型：期刊论文
| 作者 | Li, Xin-Ai; Zhou, Dong-Mei; Xu, Jing-Juan; Chen, Hong-Yuan |
| 刊名 | TALANTA
 |
| 出版日期 | 2007-02-28 |
| 卷号 | 71期号:3页码:1130-1135 |
| 关键词 | indirect amperometric detection mode heavy metal ions poly(dimethylsiloxane) microchip capillary electrophoresis carbon fibre electrode |
| ISSN号 | 0039-9140 |
| DOI | 10.1016/j.talanta.2006.06.009 |
| 通讯作者 | Xu, Jing-Juan(xujj@nju.edu.cn) |
| 英文摘要 | In-channel indirect amperometric detection mode for microchip capillary electrophoresis with positive separation electric field is successfully applied to some heavy metal ions. The influences of separation voltage, detection potential, the concentration and pH value of running buffer on the response of the detector have been investigated. An optimized condition of 1200 V separation voltage, -0.1 V detection potential, 20 mM (pH 4.46) running buffer of 2-(N-morpholino)ethanesulfonic acid (MES) + L-hisfidine (L-His) was selected. The results clearly showed that Pb(2+), Cd(2+), and Cu(2+) were efficiently separated within 80 s in a 3.7 cm long native separation PDMS/PDMS channel and successfully detected at a single carbon fibre electrode. The theoretical plate numbers of Pb(2+), Cd(2+), and Cu(2+) were 1.2 x 10(5), 2.5 x 10(5), and 1.9 x 10(5) m(-1), respectively. The detection limits for Pb(2+), Cd(2+), and Cu(2+) were 1.3, 3.3 and 7.4 mu M (S/N = 3). (c) 2006 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| WOS关键词 | CONTACTLESS CONDUCTIVITY DETECTION ; CAPILLARY-ELECTROPHORESIS ; ELECTROCHEMICAL DETECTION ; ELECTROACTIVE ANALYTES ; ELECTRODE ; SEPARATION ; ANIONS |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Analytical |
| 语种 | 英语 |
| WOS记录号 | WOS:000244536800020 |
| 出版者 | ELSEVIER SCIENCE BV |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2558648 |
| 专题 | 南京土壤研究所 |
| 通讯作者 | Xu, Jing-Juan |
| 作者单位 | 1.Nanjing Univ, Key Lab Analyt Chem Life Sci, MOE, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China 2.Chinese Acad Sci, State Key Lab Soil & Sustainable Agr, Inst Soil Sci, Nanjing 210008, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xin-Ai,Zhou, Dong-Mei,Xu, Jing-Juan,et al. In-channel indirect amperometric detection of heavy metal ions for electrophoresis on a poly(dimethylsiloxane) microchip[J]. TALANTA,2007,71(3):1130-1135. |
| APA | Li, Xin-Ai,Zhou, Dong-Mei,Xu, Jing-Juan,&Chen, Hong-Yuan.(2007).In-channel indirect amperometric detection of heavy metal ions for electrophoresis on a poly(dimethylsiloxane) microchip.TALANTA,71(3),1130-1135. |
| MLA | Li, Xin-Ai,et al."In-channel indirect amperometric detection of heavy metal ions for electrophoresis on a poly(dimethylsiloxane) microchip".TALANTA 71.3(2007):1130-1135. |
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来源：南京土壤研究所
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