中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Investigation on co-sorption and desorption of fluoride and phosphate in a red soil of China

文献类型:期刊论文

作者Zhu, Mao-Xu; Ding, Kui-Ying; Jiang, Xin; Wang, Hai-Hua
刊名WATER AIR AND SOIL POLLUTION
出版日期2007-07-01
卷号183期号:1-4页码:455-465
关键词desorption fluoride phosphrous red soil sorption surface precipitation
ISSN号0049-6979
DOI10.1007/s11270-007-9394-0
通讯作者Zhu, Mao-Xu(zhumaoxu@ouc.edu.cn)
英文摘要Agricultural soils high in both fluoride (F) and phosphate (P) are common due to long-term accumulation of F from multi-sources and extensive application of phosphate fertilizers. Iron (Fe) and aluminum (Al) (hydro)oxides in acidic soils serve as main geochemical sinks of both P and F, influencing their transport and bioavailability. Though sorption of P and F in their single-ion system has been extensively investigated, studies on co-sorption of F and P on soils are very limited. In this study, the batch technique was used to investigate mutual effects of F and P on their co-sorption/desorption in an acidic red soil with high contents of Fe and Al (hydro)oxides. Results indicate that, in F-P coexisting system, a decrease in pH enhances the sorption of both F and P. An increase in F concentration suppresses P sorption due to competitive effect. However, F sorption can be improved in the presence of P due to surface precipitation of (Al,Fe)-F-P. Sorption of F and P follows both the Langmuir and Freundlich isotherms. Different orders of F and P addition into the soil have no appreciable effect on P sorption, but exert significant impact on F sorption. The presence of F has no measurable effect on P desorption, while the stability of F in the presence of P can be significantly diminished in comparison with that in the absence of P, which would lead to an improvement of F mobility.
收录类别SCI
WOS关键词VARIABLE-CHARGE SOILS ; SURFACE PRECIPITATION ; HYDROXYALUMINUM-MONTMORILLONITE ; COMPETITIVE ADSORPTION ; PROMOTED DISSOLUTION ; ALUMINUM SMELTER ; GOETHITE ; ARSENATE ; MOBILIZATION ; CADMIUM
WOS研究方向Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences ; Water Resources
WOS类目Environmental Sciences ; Meteorology & Atmospheric Sciences ; Water Resources
语种英语
WOS记录号WOS:000247392100040
出版者SPRINGER
URI标识http://www.irgrid.ac.cn/handle/1471x/2558668
专题南京土壤研究所
通讯作者Zhu, Mao-Xu
作者单位1.Ocean Univ China, Coll Chem & Chem Engn, Qingdao 266100, Peoples R China
2.Chinese Acad Sci, Inst Soil Sci, State Key Lab Soil & Sustainable Agr, Nanjing 210008, Peoples R China
推荐引用方式
GB/T 7714
Zhu, Mao-Xu,Ding, Kui-Ying,Jiang, Xin,et al. Investigation on co-sorption and desorption of fluoride and phosphate in a red soil of China[J]. WATER AIR AND SOIL POLLUTION,2007,183(1-4):455-465.
APA Zhu, Mao-Xu,Ding, Kui-Ying,Jiang, Xin,&Wang, Hai-Hua.(2007).Investigation on co-sorption and desorption of fluoride and phosphate in a red soil of China.WATER AIR AND SOIL POLLUTION,183(1-4),455-465.
MLA Zhu, Mao-Xu,et al."Investigation on co-sorption and desorption of fluoride and phosphate in a red soil of China".WATER AIR AND SOIL POLLUTION 183.1-4(2007):455-465.

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来源:南京土壤研究所

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