中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Study on the soil mid-infrared photoacoustic spectroscopy

文献类型:期刊论文

作者Du Chang-wen; Zhou Jian-min; Wang Huo-yan; Mang Jia-bao; Zhu An-ning
刊名SPECTROSCOPY AND SPECTRAL ANALYSIS
出版日期2008-06-01
卷号28期号:6页码:1242-1245
关键词soil infrared photoacoustic spectroscopy principal components analysis soil identification
ISSN号1000-0593
通讯作者Du Chang-wen(chwdu@issas.ac.cn)
英文摘要Infrared photoacoustic spectroscopy (PAS) is a new style to obtain data based on photoacoustic theory. Photoacoustic thoeory is based on the absorption of electromagnetic radiation by analyte molecules, and the absorbed energy is measured by detecting pressure fluctuations in the form of sound waves or shock pulses. In contrast to conventional absorption spectroscopy, PAS allows the determination of absorption coefficients over several orders of magnitude, even in very black and strongly scattering soil samples. Red soil, fulvic soil and paddy soil were collected from Fengqiu National Ecological Experimental Station, Yingtan Red Soil Experimental Station, and Changshu Ecological Experimental Station, respectively. These soil samples were used as experimental materials to characterize the Fourier transform mid-infrared photoacoustic spectra (FTIR-PAS). Compared with infrared transmittance spectra and reflectance spectra, the testing of FTIR-PAS spectra was very fast and convenient with-out any pr-treatment, and there were more abundant absorptions as well as appropriate absorption values in the spectra; The main soil components (kaolin, bentonite, sand and CaCO3) also showed several strong absorptions with specific characteristics in the spectra; Further more, the interference of water with the PAS spectra was significantly smaller than that with reflectance spectra. Therefore, the soil properties could be better characterized by FTIR-PAS. The principal components analysis based on the FTIR-PAS spectra indicated that there were two main principal components (PCAI., PCA2) which contained 98.17% variance of the spectra, and the two-dimensionol distribution was made by plotting these two principal components to classify the soil type, and the results indicated that this distribution could be applied to distinguish soil type, which provided new technique for soil identification as well as further quantitative analysis in soil science.
收录类别SCI
WOS关键词DIFFUSE-REFLECTANCE SPECTROSCOPY ; FT-IR SPECTRA ; ORGANIC-MATTER ; IDENTIFICATION ; DIFFERENTIATION ; MOISTURE ; NITRATE
WOS研究方向Spectroscopy
WOS类目Spectroscopy
语种英语
WOS记录号WOS:000257356600010
出版者BEIJING UNIV PRESS
URI标识http://www.irgrid.ac.cn/handle/1471x/2558743
专题南京土壤研究所
通讯作者Du Chang-wen
作者单位Chinese Acad Sci, Inst Soil Sci, Natl Key Lab Soil & Agr Sustainabil, Nanjing 210008, Peoples R China
推荐引用方式
GB/T 7714
Du Chang-wen,Zhou Jian-min,Wang Huo-yan,et al. Study on the soil mid-infrared photoacoustic spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2008,28(6):1242-1245.
APA Du Chang-wen,Zhou Jian-min,Wang Huo-yan,Mang Jia-bao,&Zhu An-ning.(2008).Study on the soil mid-infrared photoacoustic spectroscopy.SPECTROSCOPY AND SPECTRAL ANALYSIS,28(6),1242-1245.
MLA Du Chang-wen,et al."Study on the soil mid-infrared photoacoustic spectroscopy".SPECTROSCOPY AND SPECTRAL ANALYSIS 28.6(2008):1242-1245.

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来源:南京土壤研究所

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