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The forms of alkalis in the biochar produced from crop residues at different temperatures

文献类型:期刊论文

作者Yuan, Jin-Hua1,3; Xu, Ren-Kou1; Zhang, Hong2
刊名BIORESOURCE TECHNOLOGY
出版日期2011-02-01
卷号102期号:3页码:3488-3497
关键词Alkalinity Biochar Carbonates Crop residues Amendment of acid soils
ISSN号0960-8524
DOI10.1016/j.biortech.2010.11.018
通讯作者Xu, Ren-Kou(rkxu@issas.ac.cn)
英文摘要The forms of alkalis of the biochars produced from the straws of canola, corn, soybean and peanut at different temperatures (300, 500 and 700 degrees C) were studied by means of oxygen-limited pyrolysis. The alkalinity and pH of the biochars increased with increased pyrolysis temperature. The X-ray diffraction spectra and the content of carbonates of the biochars suggested that carbonates were the major alkaline components in the biochars generated at the high temperature; they were also responsible for the strong buffer plateau-regions on the acid-base titration curves at 500 and 700 degrees C. The data of FTIR-PAS and zeta potentials indicated that the functional groups such as -COO(-) (-COOH) and -O(-) (-OH) contained by the biochars contributed greatly to the alkalinity of the biochar samples tested, especially for those generated at the lower temperature. These functional groups were also responsible for the negative charges of the biochars. (C) 2010 Elsevier Ltd. All rights reserved.
收录类别SCI
WOS关键词BLACK CARBON ; BIO-CHAR ; SOIL ; PYROLYSIS ; BIOMASS ; SPECTROSCOPY ; AMENDMENT ; ENERGY
WOS研究方向Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels
WOS类目Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels
语种英语
WOS记录号WOS:000286904500190
出版者ELSEVIER SCI LTD
URI标识http://www.irgrid.ac.cn/handle/1471x/2558928
专题南京土壤研究所
通讯作者Xu, Ren-Kou
作者单位1.Chinese Acad Sci, Inst Soil Sci, State Key Lab Soil & Sustainable Agr, Nanjing, Peoples R China
2.Tennessee Technol Univ, Dept Chem, Cookeville, TN 38505 USA
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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Yuan, Jin-Hua,Xu, Ren-Kou,Zhang, Hong. The forms of alkalis in the biochar produced from crop residues at different temperatures[J]. BIORESOURCE TECHNOLOGY,2011,102(3):3488-3497.
APA Yuan, Jin-Hua,Xu, Ren-Kou,&Zhang, Hong.(2011).The forms of alkalis in the biochar produced from crop residues at different temperatures.BIORESOURCE TECHNOLOGY,102(3),3488-3497.
MLA Yuan, Jin-Hua,et al."The forms of alkalis in the biochar produced from crop residues at different temperatures".BIORESOURCE TECHNOLOGY 102.3(2011):3488-3497.

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来源:南京土壤研究所

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