中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Charge characteristics on the clay surface with interacting electric double layers

文献类型:期刊论文

作者Jiang, X; Zhou, JM; Zhu, MX; He, WX; Yu, GF
刊名SOIL SCIENCE
出版日期2001-04-01
卷号166期号:4页码:249-254
关键词potential distribution charge density clay colloid electric double layer anion negative adsorption
ISSN号0038-075X
通讯作者Jiang, X()
英文摘要Potential distribution and charge density on the clay colloid surface with interacting double layers was solved numerically by computer using the anion negative adsorption equation. The results showed that the interacting degree of double layers affected not only the potential, Psi (d), at the midplane but also the potential Psi (delta) at the outer Helmholtz plane (OHP). The magnitude of Psi (d) increased remarkably as flat colloid particles approached each other at first and then remained almost constant at the distance of less than 70 Angstrom between two colloid particles. Therefore, it is more appropriate to use Psi (d)/Psi (delta) to describe the interacting degree of double layers than Psi (d) as in previous studies. When Psi (d)/Psi (delta) is smaller than 0.6-0.8, the surface charge density, sigma (delta), is almost unchanged with the increase of the interacting degree of electric double layers. When Psi (d)/Psi (delta) exceeds 0.6-0.8, Na+ in the diffuse layer may enter into OHP and neutralize the partial surface charge so as to lead to a reduction of the charge density at OHP. The results obtained in this paper are in good agreement with theoretical expectation.
收录类别SCI
WOS研究方向Agriculture
WOS类目Soil Science
语种英语
WOS记录号WOS:000168580200004
出版者LIPPINCOTT WILLIAMS & WILKINS
URI标识http://www.irgrid.ac.cn/handle/1471x/2559164
专题南京土壤研究所
通讯作者Jiang, X
作者单位Chinese Acad Sci, Inst Soil Sci, Dept Soil Environm Chem, Nanjing 210008, Peoples R China
推荐引用方式
GB/T 7714
Jiang, X,Zhou, JM,Zhu, MX,et al. Charge characteristics on the clay surface with interacting electric double layers[J]. SOIL SCIENCE,2001,166(4):249-254.
APA Jiang, X,Zhou, JM,Zhu, MX,He, WX,&Yu, GF.(2001).Charge characteristics on the clay surface with interacting electric double layers.SOIL SCIENCE,166(4),249-254.
MLA Jiang, X,et al."Charge characteristics on the clay surface with interacting electric double layers".SOIL SCIENCE 166.4(2001):249-254.

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来源:南京土壤研究所

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