Interfacing cytochrome c to Au electrodes with humic acid film
文献类型：期刊论文
| 作者 | Xu, JJ; Wang, G; Zhang, Q; Zhou, DM; Chen, HY |
| 刊名 | ELECTROCHEMISTRY COMMUNICATIONS
 |
| 出版日期 | 2004-03-01 |
| 卷号 | 6期号:3页码:278-283 |
| 关键词 | humic acid microrods cytochrome c direct electron transfer self-assembled monolayer |
| ISSN号 | 1388-2481 |
| DOI | 10.1016/j.elecom.2004.01.001 |
| 通讯作者 | Chen, HY() |
| 英文摘要 | Humic acid (HA) films were formed on a gold electrode surface by the self-assembly method. The HA films were used as an immobilization matrix interfacing cytochrome c (cyt c) to An electrode surface through a dip and phase inversion process. The morphologies of the films, changes of structure and properties of the electrochemistry were investigated by scanning electron microscope (SEM), UV-Vis spectroscopy (UV-Vis) and electrochemical impedance spectroscopy (EIS) and cyclic voltammetry. The results showed that the HA film acted as a good adsorption matrix for cyt c and an excellent accelerant for the redox of cyt c which gives reversible redox peaks with a formal potential of 108 mV vs SCE in pH 7.0 phosphate buffer solution. The average surface coverage of cyt c on the HA film was about 3.49x10(-11) mol/cm(2), indicating a monolayer of cyt c. The electron transfer rate constant was calculated to be 1.0 s(-1). (C) 2004 Elsevier B.V. All rights reserved. |
| 收录类别 | SCI |
| WOS关键词 | CARBON-PASTE ELECTRODE ; SURFACE-ACTIVE SUBSTANCES ; ATOMIC-FORCE MICROSCOPY ; ELECTROCHEMICAL-BEHAVIOR ; AQUEOUS-SOLUTION ; METAL-IONS ; IN-SITU ; MERCURY ; ADSORPTION ; GOLD |
| WOS研究方向 | Electrochemistry |
| WOS类目 | Electrochemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000189124800011 |
| 出版者 | ELSEVIER SCIENCE INC |
| URI标识 | http://www.irgrid.ac.cn/handle/1471x/2559353 |
| 专题 | 南京土壤研究所 |
| 通讯作者 | Chen, HY |
| 作者单位 | 1.Nanjing Univ, Dept Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China 2.Chinese Acad Sci, Inst Soil Sci, Nanjing 210008, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, JJ,Wang, G,Zhang, Q,et al. Interfacing cytochrome c to Au electrodes with humic acid film[J]. ELECTROCHEMISTRY COMMUNICATIONS,2004,6(3):278-283. |
| APA | Xu, JJ,Wang, G,Zhang, Q,Zhou, DM,&Chen, HY.(2004).Interfacing cytochrome c to Au electrodes with humic acid film.ELECTROCHEMISTRY COMMUNICATIONS,6(3),278-283. |
| MLA | Xu, JJ,et al."Interfacing cytochrome c to Au electrodes with humic acid film".ELECTROCHEMISTRY COMMUNICATIONS 6.3(2004):278-283. |
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来源：南京土壤研究所
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