High thermoelectric performance of n-type Bi(2)Te(2.7)Se(0.3)via nanostructure engineering
文献类型:期刊论文
作者 | Li, D.1; Li, J. M.1,2; Li, J. C.1; Wang, Y. S.1; Zhang, J.1; Qin, X. Y.1; Cao, Y.3; Li, Y. S.3; Tang, G. D.3 |
刊名 | JOURNAL OF MATERIALS CHEMISTRY A |
出版日期 | 2018-05-28 |
卷号 | 6期号:20页码:9642-9649 |
ISSN号 | 2050-7488 |
DOI | 10.1039/c8ta00525g |
英文摘要 | BiSbTe has been realized as an ideal p-type thermoelectric material near room temperature; however, its commercial applications are largely restricted by its n-type counterpart that exhibits relatively inferior thermoelectric performance. In this work, n-type BiTeSe based composites Bi2Te2.7Se0.3-f InSb (0 f 2.5 vol%) are prepared by a ball milling and spark plasma sintering method. A record-high ZT value of approximate to 1.22 is achieved at 323 K for Bi2Te2.7Se0.3-1.5 vol% InSb composites. This significant enhancement in thermoelectric performance is attributed to the incorporation of nanostructured InSb into the Bi2Te2.7Se0.3 matrix, which can simultaneously modulate the electrical and thermal transport. InSb with high carrier mobility precipitated in the matrix can strengthen interface scattering at the phase boundaries, which can effectively scatter the heat-carrying phonons and thus yield an extremely low lattice thermal conductivity, while the high power factor is maintained. As a result, a maximum ZT of 1.22 is obtained. The average ZT in the temperature range of 300-425 K for Bi2Te2.7Se0.3-1.5 vol% InSb is 1.14, which is at least 15% larger than that of previously reported values. Our results demonstrate that for n-type bismuth-telluride-based alloys, imbedding nanostructured phases with a high carrier mobility is an effective strategy for enhancing the performance of the state-of-the-art thermoelectric systems. |
WOS关键词 | POINT-DEFECTS ; NANOCOMPOSITES ; SCATTERING ; BISBTE |
资助项目 | Natural Science Foundation of China[51672278] ; Natural Science Foundation of China[11674322] ; AnHui Provincial Natural Science Foundation[1608085MA17] ; Natural Science Foundation of China[11374306] ; Institute of Solid State Physics[2016DFS01] ; Institute of Solid State Physics[2016DFY01] ; Institute of Solid State Physics[2016DFY11] |
WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
语种 | 英语 |
出版者 | ROYAL SOC CHEMISTRY |
WOS记录号 | WOS:000433427300034 |
源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/36506] |
专题 | 合肥物质科学研究院_中科院固体物理研究所 中科院固体物理研究所_专题未命名 |
通讯作者 | Li, D.; Zhang, J.; Qin, X. Y. |
作者单位 | 1.Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Anhui, Peoples R China 2.Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China 3.Nanjing Univ Sci & Technol, Sch Mat Sci & Engn, Nanjing 210094, Jiangsu, Peoples R China |
推荐引用方式 GB/T 7714 | Li, D.,Li, J. M.,Li, J. C.,et al. High thermoelectric performance of n-type Bi(2)Te(2.7)Se(0.3)via nanostructure engineering[J]. JOURNAL OF MATERIALS CHEMISTRY A,2018,6(20):9642-9649. |
APA | Li, D..,Li, J. M..,Li, J. C..,Wang, Y. S..,Zhang, J..,...&Tang, G. D..(2018).High thermoelectric performance of n-type Bi(2)Te(2.7)Se(0.3)via nanostructure engineering.JOURNAL OF MATERIALS CHEMISTRY A,6(20),9642-9649. |
MLA | Li, D.,et al."High thermoelectric performance of n-type Bi(2)Te(2.7)Se(0.3)via nanostructure engineering".JOURNAL OF MATERIALS CHEMISTRY A 6.20(2018):9642-9649. |
入库方式: OAI收割
来源:合肥物质科学研究院
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