High-energy nanostructured Na3V2(PO4)(2)O1.6F1.4 cathodes for sodium-ion batteries and a new insight into their redox chemistry
文献类型：期刊论文
| 作者 | Li, Chao1; Shen, Ming1; Hu, Bei1; Lou, Xiaobing1; Zhang, Xi2; Tong, Wei3 ; Hu, Bingwen1
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| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
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| 出版日期 | 2018-05-14 |
| 卷号 | 6期号:18页码:8340-8348 |
| ISSN号 | 2050-7488 |
| DOI | 10.1039/c8ta00568k |
| 英文摘要 | A microwave-assisted solvothermal procedure is employed for the rapid fabrication of nanostructured Na3V2(PO4)(2)O1.6F1.4 with a space group of 14/mmm. This Na3V2(PO4)(2)O1.6F1.4 exhibits a high energy density (518 W h kg(-1)) and impressive power performance (11 127 W kg(-1) while retaining an energy density of 306 W h kg(-1)) in Na-ion coin cells. Furthermore, the redox chemistry of Na3V2(PO4)(2)O1.6F1.4 was investigated by combination of electron paramagnetic resonance and X-ray diffraction techniques. The results substantiate that: (i) both V-3/V4+ and V-4/V5+ couples are active in this Na3V2(PO4)(2)O1.6F1.4, corresponding to a total amount of 2 electrons transferred per formula unit; (ii) the Na extraction/intercalation process is mainly a solid-solution mechanism. |
| WOS关键词 | HIGH-PERFORMANCE CATHODE ; ELECTROCHEMICAL PERFORMANCE ; STRUCTURAL EVOLUTION ; ELECTRODE MATERIALS ; RATE CAPABILITY ; FLUOROPHOSPHATE ; GRAPHENE ; STORAGE ; SPECTRA ; NMR |
| 资助项目 | National Natural Science Foundation of China for Excellent Young Scholars[21522303] ; National Natural Science Foundation of China[21373086] ; ECNU Outstanding Doctoral Dissertation Cultivation Plan of Action[YB2016031] ; Steady High Magnetic Field Facilities of the High Magnetic Field Laboratory |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000434624800022 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.hfcas.ac.cn:8080/handle/334002/36789]  |
| 专题 | 合肥物质科学研究院_中科院强磁场科学中心 |
| 通讯作者 | Hu, Bingwen |
| 作者单位 | 1.East China Normal Univ, Sch Phys & Mat Sci, Shanghai Key Lab Resonance, Inst Funct Mat,State Key Lab Precis Spect, Shanghai 200062, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China 3.Chinese Acad Sci, High Magnet Field Lab, Anhui Key Lab Condensed Matter Phys Extreme Condi, Hefei 230031, Anhui, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Chao,Shen, Ming,Hu, Bei,et al. High-energy nanostructured Na3V2(PO4)(2)O1.6F1.4 cathodes for sodium-ion batteries and a new insight into their redox chemistry[J]. JOURNAL OF MATERIALS CHEMISTRY A,2018,6(18):8340-8348. |
| APA | Li, Chao.,Shen, Ming.,Hu, Bei.,Lou, Xiaobing.,Zhang, Xi.,...&Hu, Bingwen.(2018).High-energy nanostructured Na3V2(PO4)(2)O1.6F1.4 cathodes for sodium-ion batteries and a new insight into their redox chemistry.JOURNAL OF MATERIALS CHEMISTRY A,6(18),8340-8348. |
| MLA | Li, Chao,et al."High-energy nanostructured Na3V2(PO4)(2)O1.6F1.4 cathodes for sodium-ion batteries and a new insight into their redox chemistry".JOURNAL OF MATERIALS CHEMISTRY A 6.18(2018):8340-8348. |
入库方式： OAI收割
来源：合肥物质科学研究院
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