Xylogranatins F-R: Antifeedants from the chinese mangrove, Xylocarpus granatum, a new biogenetic pathway to tetranortriterpenoids
文献类型：期刊论文
| 作者 | wwujun2003@yahoo.com; Wu, J; Zhang, S; Bruhn, T; Xiao, Q; Ding, HX; Bringmann, G; bringmann@chemie.uni-wuerzburg.de |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2008 |
| 卷号 | 14期号:4页码:1129-1144 |
| 关键词 | Antifeedant Activity Biosynthesis Configuration Determination Natural Products Xylogranatins |
| ISSN号 | 0947-6539 |
| 英文摘要 | Thirteen limonoids with a new carbon skeleton, the xylogranatins F-R (1-13), have been isolated from the seeds of a Chinese mangrove, Xylocarpus granatum; two recently reported compounds, xylogranatins C and D were also isolated. Their structures were elucidated on the basis of spectroscopic data and chemical methods. The absolute configurations of these compounds were determined by using the modified Mosher MTPA ester method and by quantum chemical circular dichroism (CD) calculations. Xylogranatins F-Q are the first aromatic B-ring limonoids found in nature. They belong to two substructural classes, of which one (1-3) contains a pyridine ring while the other one (412) contains a central furan core. Xylogranatins C and R can be considered to be key biosynthetic intermediates, while xylogranatin D, the only limonoid found so far with a carbon skeleton that conatains a C-30-C-9 linkage, is apparently an artifact. The structures of these compounds suggest a new biogenetic pathway to tetranortriterpenoids. Xylogranatins F, G and R were found to exhibit marked antifeedant activity against the third instar larvae of Mythimna separata (Walker) at a concentration of 1 mg mL(-1). The most potent compound tested was xylogranatin G. Its AFC(50) (concentration for 50% antifeedant activity) values at the exposure times of 24 and 48 h were 0.31 and 0.30 mg mL(-1), respectively. |
| 学科主题 | Chemistry, Multidisciplinary |
| 资助项目 | LMB |
| WOS记录号 | WOS:000252879800007 |
| 公开日期 | 2011-07-03 |
| 源URL | [http://ir.scsio.ac.cn/handle/344004/5012]  |
| 专题 | 南海海洋研究所_中科院海洋生物资源可持续利用重点实验室 |
| 通讯作者 | wwujun2003@yahoo.com; bringmann@chemie.uni-wuerzburg.de |
| 推荐引用方式 GB/T 7714 | wwujun2003@yahoo.com,Wu, J,Zhang, S,et al. Xylogranatins F-R: Antifeedants from the chinese mangrove, Xylocarpus granatum, a new biogenetic pathway to tetranortriterpenoids[J]. CHEMISTRY-A EUROPEAN JOURNAL,2008,14(4):1129-1144. |
| APA | wwujun2003@yahoo.com.,Wu, J.,Zhang, S.,Bruhn, T.,Xiao, Q.,...&bringmann@chemie.uni-wuerzburg.de.(2008).Xylogranatins F-R: Antifeedants from the chinese mangrove, Xylocarpus granatum, a new biogenetic pathway to tetranortriterpenoids.CHEMISTRY-A EUROPEAN JOURNAL,14(4),1129-1144. |
| MLA | wwujun2003@yahoo.com,et al."Xylogranatins F-R: Antifeedants from the chinese mangrove, Xylocarpus granatum, a new biogenetic pathway to tetranortriterpenoids".CHEMISTRY-A EUROPEAN JOURNAL 14.4(2008):1129-1144. |
入库方式： OAI收割
来源：南海海洋研究所
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