中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A study on the reaction of Zincon-Cu(II) metal complexes with bovine serum albumin

文献类型:期刊论文

作者Wang, XM ; Dong, FQ ; Ding, LS ; Peng, RF ; Liao, HW
刊名CHINESE JOURNAL OF INORGANIC CHEMISTRY
出版日期2004
卷号20期号:8页码:920_924
关键词ZCN-Cu(II) coordination compound bovine serum albumin(BSA) UV-Vis spectra ZCN-Cu(II)-bovine serum albumin coordination compound
ISSN号1001-4861
产权排序2
通讯作者Wang, XM, SW Univ Sci & Technol, Dept Chem & Biol Engn, Mianyang 621002, South Korea.
中文摘要The interaction of Zincon(ZCN)-Cu(II) metal complexe with bovine serum albumin (BSA) was investigated by UV-Vis spectrophotometric method in acidic buffer solution (pH=4.25). ZCN-Cu(II)-BSA was a blueness color coordination compound, with maximum absorption at 605 nm with 10 nm, 60 nm and 140 nm of red shift compared to the ZCN-Cu(II) complex, ZCN-BSA complex and ZCN. According to molar ratio method and dual wavelength method, the apparent molar absorptivity of epsilon was equal to 4.82x10(5) L.mol(-1).cm(-1). Conditional constants were defined as ZCN:Cu(II):BSA=10:5:2. Condition combination constant of ZCN-Cu(II) and BSA K was 8.82x10(4). A combined mechanism was suggested between BSA and ZCN-Cu(II) by electrostatic force (Primary action force) and distant water force. Position of Impact might be arginine, proline, histidine, tyrosine and cystine. Contemporary formation of electron transfer complexes is an important cause in forming ZCN-Cu(II)-BSA complexes.
学科主题Chemistry, Inorganic & Nuclear
收录类别SCI
语种中文
WOS记录号WOS:000223096200008
公开日期2011-07-08
源URL[http://210.75.237.14/handle/351003/17481]  
专题成都生物研究所_天然产物研究
推荐引用方式
GB/T 7714
Wang, XM,Dong, FQ,Ding, LS,et al. A study on the reaction of Zincon-Cu(II) metal complexes with bovine serum albumin[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2004,20(8):920_924.
APA Wang, XM,Dong, FQ,Ding, LS,Peng, RF,&Liao, HW.(2004).A study on the reaction of Zincon-Cu(II) metal complexes with bovine serum albumin.CHINESE JOURNAL OF INORGANIC CHEMISTRY,20(8),920_924.
MLA Wang, XM,et al."A study on the reaction of Zincon-Cu(II) metal complexes with bovine serum albumin".CHINESE JOURNAL OF INORGANIC CHEMISTRY 20.8(2004):920_924.

入库方式: OAI收割

来源:成都生物研究所

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