Inorganic/organic salts as heterogeneous basic catalysts for cyanosilylation of carbonyl compounds
文献类型：期刊论文
| 作者 | He, B ; Li, Y ; Feng, XM ; Zhang, GL |
| 刊名 | SYNLETT
 |
| 出版日期 | 2004 |
| 期号 | 10页码:1776_1778 |
| 关键词 | heterogeneous catalysis potassium carbonate cyanosilylation cyanohydrins carbonyl compounds |
| ISSN号 | 0936-5214 |
| 产权排序 | 3 |
| 通讯作者 | Feng, XM, Sichuan Univ, Coll Chem, Minist Educ, Key LGreen Chem & Technol, Chengdu 610064, Peoples R China. |
| 中文摘要 | The addition of TMSCN to carbonyl compounds catalyzed by K2CO3 as heterogeneous catalyst gave the corresponding cyanohydrin trimethylsilyl ethers from 20 minutes to 24 hours with 62% to 99% yields without solvent at room temperature. Moreover, it was found that chiral organic salts as heterogeneous catalysts also can catalyze the asymmetric version and afford the corresponding products with up to 99% yield and 12.4% ee. |
| 学科主题 | Chemistry, Organic |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000223328700027 |
| 公开日期 | 2011-07-08 |
| 源URL | [http://210.75.237.14/handle/351003/17511]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 推荐引用方式 GB/T 7714 | He, B,Li, Y,Feng, XM,et al. Inorganic/organic salts as heterogeneous basic catalysts for cyanosilylation of carbonyl compounds[J]. SYNLETT,2004(10):1776_1778. |
| APA | He, B,Li, Y,Feng, XM,&Zhang, GL.(2004).Inorganic/organic salts as heterogeneous basic catalysts for cyanosilylation of carbonyl compounds.SYNLETT(10),1776_1778. |
| MLA | He, B,et al."Inorganic/organic salts as heterogeneous basic catalysts for cyanosilylation of carbonyl compounds".SYNLETT .10(2004):1776_1778. |
入库方式： OAI收割
来源：成都生物研究所
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